Cu–Pd/Zeolite as Efficient Thermo‐Catalyst to Oxidize Low‐Concentration Methane

Abstract Although methane (CH 4 ) predominantly exists in low concentration, it contributes significantly to global warming and just second to CO 2 . Its inert characteristics present both a pressing need and a significant challenge for mitigation strategies, including thermal catalytic oxidation. To address this challenge, we synthesized low cost mordenite zeolite (MOR) with highly dispersed Cu–Pd (Pd: 0.10 wt%) as efficient thermo‐catalyst to oxidize low‐concentration CH 4 (200 ppm). The Cu–Pd–MOR catalyst achieves 90% CH 4 conversion at 358 °C and exhibits improved durability over 100 h of continuous operation. Incorporating Cu enables reduction in Pd loading while maintaining high activity, demonstrating a synergistic Cu–Pd interaction that enhances metal dispersion and thermal stability. Compared with Pd‐only MOR catalysts, the Cu–Pd system delivers advanced low‐temperature activity and long‐term stability, offering a cost‐effective route for methane removal.

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Publication Details

Journal
ChemCatChem
Published
2025-12-04
DOI
https://doi.org/10.1002/cctc.202501459
Primary Topic
Catalytic Processes in Materials Science
Type
article
Field-Weighted Citation Impact
0.00

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article

Cu–Pd/Zeolite as Efficient Thermo‐Catalyst to Oxidize Low‐Concentration Methane

Lin Yao, Y Wang, Xianfeng Fan, Xiaohua Lü et al.
ChemCatChem
Catalytic Processes in Materials Science
article

Cu–Pd/Zeolite as Efficient Thermo‐Catalyst to Oxidize Low‐Concentration Methane

Lin Yao, Y Wang, Xianfeng Fan, Xiaohua Lü, Liwen Mu, Wei Li, Zihan Liu, Tingzhen Ming, Ying Li, Yun Wang
article en

Abstract

Abstract Although methane (CH 4 ) predominantly exists in low concentration, it contributes significantly to global warming and just second to CO 2 . Its inert characteristics present both a pressing need and a significant challenge for mitigation strategies, including thermal catalytic oxidation. To address this challenge, we synthesized low cost mordenite zeolite (MOR) with highly dispersed Cu–Pd (Pd: 0.10 wt%) as efficient thermo‐catalyst to oxidize low‐concentration CH 4 (200 ppm). The Cu–Pd–MOR catalyst achieves 90% CH 4 conversion at 358 °C and exhibits improved durability over 100 h of continuous operation. Incorporating Cu enables reduction in Pd loading while maintaining high activity, demonstrating a synergistic Cu–Pd interaction that enhances metal dispersion and thermal stability. Compared with Pd‐only MOR catalysts, the Cu–Pd system delivers advanced low‐temperature activity and long‐term stability, offering a cost‐effective route for methane removal.

ChemCatChemVol. 18(1)
Sinopec (China) (CN), Nanjing Tech University (CN), Shanghai Jiao Tong University (CN), Wuhan University of Technology (CN), University of Edinburgh (GB)
European Commission, Shanghai Jiao Tong University, Horizon 2020 Framework Programme
Openalex Percentile: Top 68%
Catalytic Processes in Materials Science
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