Cu–Pd/Zeolite as Efficient Thermo‐Catalyst to Oxidize Low‐Concentration Methane
Abstract Although methane (CH 4 ) predominantly exists in low concentration, it contributes significantly to global warming and just second to CO 2 . Its inert characteristics present both a pressing need and a significant challenge for mitigation strategies, including thermal catalytic oxidation. To address this challenge, we synthesized low cost mordenite zeolite (MOR) with highly dispersed Cu–Pd (Pd: 0.10 wt%) as efficient thermo‐catalyst to oxidize low‐concentration CH 4 (200 ppm). The Cu–Pd–MOR catalyst achieves 90% CH 4 conversion at 358 °C and exhibits improved durability over 100 h of continuous operation. Incorporating Cu enables reduction in Pd loading while maintaining high activity, demonstrating a synergistic Cu–Pd interaction that enhances metal dispersion and thermal stability. Compared with Pd‐only MOR catalysts, the Cu–Pd system delivers advanced low‐temperature activity and long‐term stability, offering a cost‐effective route for methane removal.
Authors
- Lin Yao (ORCID: https://orcid.org/0000-0002-5025-627X)
- Y Wang (ORCID: https://orcid.org/0000-0002-2664-570X)
- Xianfeng Fan (ORCID: https://orcid.org/0000-0002-6811-953X)
- Xiaohua Lü (ORCID: https://orcid.org/0000-0001-9244-6808)
- Liwen Mu (ORCID: https://orcid.org/0000-0002-4893-0886)
- Wei Li (ORCID: https://orcid.org/0000-0003-4036-467X)
- Zihan Liu (ORCID: https://orcid.org/0000-0002-7551-6859)
- Tingzhen Ming
- Ying Li (ORCID: https://orcid.org/0000-0003-3143-359X)
- Yun Wang (ORCID: https://orcid.org/0009-0006-5841-3627)
Institutions
- Sinopec (China) (CN)
- Nanjing Tech University (CN)
- Shanghai Jiao Tong University (CN)
- Wuhan University of Technology (CN)
- University of Edinburgh (GB)
Publication Details
- Journal
- ChemCatChem
- Published
- 2025-12-04
- DOI
- https://doi.org/10.1002/cctc.202501459
- Primary Topic
- Catalytic Processes in Materials Science
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- European Commission
- Shanghai Jiao Tong University
- Horizon 2020 Framework Programme