Force-Free Kinetic Inference of Entropy Production

Estimating entropy production, which quantifies irreversibility and energy dissipation, remains a significant challenge despite its central role in nonequilibrium physics. We propose a novel method for estimating the mean entropy production rate σ that relies solely on position traces, bypassing the need for flux or microscopic force measurements. Starting from a recently introduced variance sum rule, we express σ in terms of measurable steady-state correlation functions that we link to previously studied kinetic quantities, known as "traffic" and "inflow rate." Under realistic constraints of limited access to dynamical degrees of freedom, we derive efficient bounds on σ by leveraging the information contained in the system's traffic, enabling partial but meaningful estimates of σ. We benchmark our results across several orders of magnitude in σ using two models: a linear stochastic system and a nonlinear model for spontaneous hair-bundle oscillations. Our approach offers a practical and versatile framework for investigating entropy production in nonequilibrium systems.

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Publication Details

Journal
Physical Review Letters
Published
2025-11-12
DOI
https://doi.org/10.1103/fsph-437v
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
Field-Weighted Citation Impact
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article

Force-Free Kinetic Inference of Entropy Production

Ivan Di Terlizzi
Physical Review Letters
Advanced Thermodynamics and Statistical Mechanics
article

Force-Free Kinetic Inference of Entropy Production

Ivan Di Terlizzi
article en

Abstract

Estimating entropy production, which quantifies irreversibility and energy dissipation, remains a significant challenge despite its central role in nonequilibrium physics. We propose a novel method for estimating the mean entropy production rate σ that relies solely on position traces, bypassing the need for flux or microscopic force measurements. Starting from a recently introduced variance sum rule, we express σ in terms of measurable steady-state correlation functions that we link to previously studied kinetic quantities, known as "traffic" and "inflow rate." Under realistic constraints of limited access to dynamical degrees of freedom, we derive efficient bounds on σ by leveraging the information contained in the system's traffic, enabling partial but meaningful estimates of σ. We benchmark our results across several orders of magnitude in σ using two models: a linear stochastic system and a nonlinear model for spontaneous hair-bundle oscillations. Our approach offers a practical and versatile framework for investigating entropy production in nonequilibrium systems.

Physical Review LettersVol. 135(23)
Max Planck Institute for the Physics of Complex Systems (DE)
Openalex Percentile: Top 69%
Advanced Thermodynamics and Statistical Mechanics
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Force-Free Kinetic Inference of Entropy Production — Ivan Di Terlizzi · Physical Review Letters (2025) | TGRS Research Map | TGRS