Annulated oxazolium salts as anion–π <sup>+</sup> interaction-enabled solid-state room-temperature phosphorescent materials

Efficient counter-anion exchange represents a powerful and straightforward approach for modulating the photophysical properties of ionic luminescent materials without structural modification. Herein, we report how fluorescent annulated oxazolium salts switched to room-temperature phosphorescent materials upon counter-anion exchange of hexafluorophosphate (PF<sub>6</sub><sup>-</sup>) with iodide (I<sup>-</sup>).

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Publication Details

Journal
Chemical Communications
Published
2025-12-05
DOI
https://doi.org/10.1039/d5cc05870h
Primary Topic
Inorganic Chemistry and Materials
Type
article
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article

Annulated oxazolium salts as anion–π + interaction-enabled solid-state room-temperature phosphorescent materials

Joyanta Choudhury, Samim Sohel Rana, Chhotan Barman, Shivankar Jagota
Chemical Communications
Inorganic Chemistry and Materials
article

Annulated oxazolium salts as anion–π + interaction-enabled solid-state room-temperature phosphorescent materials

Joyanta Choudhury, Samim Sohel Rana, Chhotan Barman, Shivankar Jagota
article en

Abstract

Efficient counter-anion exchange represents a powerful and straightforward approach for modulating the photophysical properties of ionic luminescent materials without structural modification. Herein, we report how fluorescent annulated oxazolium salts switched to room-temperature phosphorescent materials upon counter-anion exchange of hexafluorophosphate (PF<sub>6</sub><sup>-</sup>) with iodide (I<sup>-</sup>).

Chemical CommunicationsVol. 62(4)
Indian Institute of Science Education and Research, Bhopal (IN)
Openalex Percentile: Top 68%
Inorganic Chemistry and Materials
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