Study on the Effectiveness of Perfluorohexanone in Extinguishing Small-Scale Pool Fires in Enclosed Compartments Under Low-Pressure Conditions

To investigate the fire suppression effectiveness of perfluorohexanone in low-pressure environments, a self-built fire suppression experimental platform was utilized to analyze the influence of ambient pressure and heat release rate on its performance. The results demonstrate that under normal-pressure conditions, the extinguishing time increases with the heat release rate of the fire source, whereas under low-pressure conditions, the extinguishing time decreases as the heat release rate increases. Specifically, under normal pressure, the extinguishing times for Fire Pan A (10 cm × 10 cm × 10 cm), Fire Pan B (15 cm × 15 cm × 10 cm), and Fire Pan C (20 cm × 20 cm × 10 cm) were 5.03 s, 8.15 s, and 9.63 s, respectively. In contrast, under low pressure, the extinguishing times were significantly shorter, with reductions of 2.8 s, 6.59 s, and 8.45 s, respectively. In terms of temperature reduction, the flame temperature decreased by approximately 300 °C under normal pressure, while under low pressure, it decreased by only about 100 °C. The concentration of hydrogen fluoride (HF) produced after extinguishment was relatively low, indicating limited toxicity. The HF concentration under normal pressure was, on average, approximately 59.2% higher than that under low-pressure conditions. Based on parameters such as the mass of the extinguishing agent, temperature changes, and hydrogen fluoride content, a fire suppression effectiveness model was established. The results show that the weight coefficient for chemical inhibition intensity is as high as 38.81, significantly exceeding other factors, demonstrating that perfluorohexanone primarily relies on chemical inhibition to interrupt the combustion chain reaction. This conclusion provides an important theoretical basis for the design and optimization of fire suppression systems in low-pressure environments such as aviation and high-altitude areas.