Preparation of Biochar from Papermaking Sludge and Its Adsorption Characteristics for Tetracycline

Papermaking sludge, rich in intrinsic resource value, is effectively barred from direct deployment in environmental remediation, agriculture, or energy generation by its pronounced contaminant burden. Pyrolytic conversion into high-value paper sludge biochar, such as papermaking sludge biochar (PSBC) provides a green, efficient portal for closing its resource loop. In this study, papermaking sludge was converted into a series of paper sludge biochars (PSBCs) via oxygen-limited pyrolysis at 500-900 °C. The porous architecture, surface physicochemical properties, and crystalline structure of the biochars were comprehensively characterized, and their performance for aqueous tetracycline (TC) removal was systematically quantified. Pyrolysis at 900 °C afforded PSBC 900 with the lowest yield (36.05%) yet the highest Brunauer-Emmett-Teller (BET) surface area (79.53 m²/g), an extensively developed mesopore network, and the greatest degree of graphitization. Across an initial tetracycline (TC) concentration window of 20-160 mg/L, PSBC 900 delivered an equilibrium capacity (q_e) of 72.22 mg/g, outperforming PSBC 700 and PSBC 500 by factors of 1.3 and 1.8, respectively. Optimal uptake was achieved at a dosage of 1.0 g/L, pH 7, and 120 min contact time. Among the background cations examined, Mg²⁺ exerted a pronounced inhibitory effect, whereas Na⁺, K⁺, and Ca²⁺ exerted negligible interference. The adsorption process was accurately described by the pseudo-second-order kinetic model and the Langmuir isotherm (R² > 0.999), yielding a theoretical maximum capacity (q_m) of 76.39 mg/g for PSBC 900 at 313 K. Thermodynamic parameters (∆Gθ < 0, ∆Hθ > 0, ∆Sθ > 0) confirm a spontaneous, endothermic, and entropy-driven process. After five consecutive adsorption-desorption cycles, PSBC 900 retained >64.68% of its original efficiency, demonstrating excellent regenerability. Paper sludge biochar enables a "waste-to-treat-waste" strategy for the efficient abatement of tetracycline, offering an economically viable and high-performance technology that advances the remediation of tetracycline-laden wastewaters.