Variational studies of the rovibrational spectra of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:msup> <mml:mrow> <mml:mi>DT</mml:mi> </mml:mrow> <mml:mo>+</mml:mo> </mml:msup> </mml:math> and <mml:math xmlns:mml="http://www.w3.org/
In this work we study the last two hydrogen molecular ion isotopologues, ${\mathrm{DT}}^{+}$ and ${\mathrm{T}}_{2}^{+}$, for which high-precision calculations have not yet been made. We obtain the nonrelativistic solutions of the Schr"odinger equation for the wide range of vibrational states up to the highest possible vibrational $1s{\ensuremath{\sigma}}_{g}$ state which are of spectroscopic precision. Transition amplitudes for electric dipole transitions, leading-order relativistic corrections, and coefficients of the effective hyperfine structure Hamiltonians for both ${\mathrm{DT}}^{+}$ and ${\mathrm{T}}_{2}^{+}$ are also calculated.
Authors
- D. Aznabayev (ORCID: https://orcid.org/0000-0001-5065-1299)
- A. K. Bekbaev (ORCID: https://orcid.org/0000-0003-4800-357X)
- V. I. Korobov (ORCID: https://orcid.org/0000-0003-3724-0270)
- D. B. Zhomartova
Institutions
- Al-Farabi Kazakh National University (KZ)
- Joint Institute for Nuclear Research (RU)
- National Nuclear Center of the Republic of Kazakhstan (KZ)
Publication Details
- Journal
- Physical review. A/Physical review, A
- Published
- 2025-11-10
- DOI
- https://doi.org/10.1103/7klt-y4rh
- Primary Topic
- Atomic and Molecular Physics
- Type
- article
- Field-Weighted Citation Impact
- 0.00