Metal-free regioselective B–O coupling in carboranes for constructing aggregation-induced emission luminogens

We report a metal-free regioselective B-O coupling of <i>nido</i>-carboranes enabled by hypervalent iodine(III) under mild conditions. This method establishes a new synthetic platform for the rapid assembly of carborane-based aggregation-induced emission (AIE) luminogens.

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Publication Details

Journal
Chemical Communications
Published
2025-12-04
DOI
https://doi.org/10.1039/d5cc03944d
Primary Topic
Boron Compounds in Chemistry
Type
article
Field-Weighted Citation Impact
0.00
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article

Metal-free regioselective B–O coupling in carboranes for constructing aggregation-induced emission luminogens

Deshuang Tu, Hong Yan, Changsheng Lu, Xinrui Li et al.
Chemical Communications
Boron Compounds in Chemistry
article

Metal-free regioselective B–O coupling in carboranes for constructing aggregation-induced emission luminogens

Deshuang Tu, Hong Yan, Changsheng Lu, Xinrui Li, Ningning Zhou
article en

Abstract

We report a metal-free regioselective B-O coupling of <i>nido</i>-carboranes enabled by hypervalent iodine(III) under mild conditions. This method establishes a new synthetic platform for the rapid assembly of carborane-based aggregation-induced emission (AIE) luminogens.

Chemical CommunicationsVol. 62(2)
Nanjing University (CN)
Openalex Percentile: Top 47%
Boron Compounds in Chemistry
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