Lewis acid-catalysed cyclization of pyridinium 1,4-zwitterionic thiolates with propargyl alcohols and fluorescence applications

A new method for the efficient synthesis of thieno[3,4-<i>c</i>]furan-1-one derivatives through an intermolecular annulation strategy is reported. With an appropriate combination of Cu(OTf)<sub>2</sub> and 13X molecular sieves, a range of organosulfur compounds were obtained in good yields. Most of the obtained products exhibited good photophysical properties, and thieno[3,4-<i>c</i>]furan-4-carboxylate could be identified as a fluorescence sensor for Fe<sup>3+</sup>.

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Publication Details

Journal
Chemical Communications
Published
2025-12-04
DOI
https://doi.org/10.1039/d5cc06010a
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
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article

Lewis acid-catalysed cyclization of pyridinium 1,4-zwitterionic thiolates with propargyl alcohols and fluorescence applications

Zi‐Xin You, Xuesong Li, Zhiyuan Yang, Mingli Zhang et al.
Chemical Communications
Sulfur-Based Synthesis Techniques
article

Lewis acid-catalysed cyclization of pyridinium 1,4-zwitterionic thiolates with propargyl alcohols and fluorescence applications

Zi‐Xin You, Xuesong Li, Zhiyuan Yang, Mingli Zhang, Mingdong Zhou, Yong‐Min Liang
article en

Abstract

A new method for the efficient synthesis of thieno[3,4-<i>c</i>]furan-1-one derivatives through an intermolecular annulation strategy is reported. With an appropriate combination of Cu(OTf)<sub>2</sub> and 13X molecular sieves, a range of organosulfur compounds were obtained in good yields. Most of the obtained products exhibited good photophysical properties, and thieno[3,4-<i>c</i>]furan-4-carboxylate could be identified as a fluorescence sensor for Fe<sup>3+</sup>.

Chemical CommunicationsVol. 62(14)
Shenyang University of Chemical Technology (CN), Lanzhou University (CN)
Openalex Percentile: Top 71%
Sulfur-Based Synthesis Techniques
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Lewis acid-catalysed cyclization of pyridinium 1,4-zwitterionic thiolates with propargyl alcohols and fluorescence applications — Zi‐Xin You, Xuesong Li, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS