Estimating the Groundwater Recharge Sources to Spring-Fed Lake Ezu, Kumamoto City, Japan from Hydrochemical Characteristics

Kumamoto is a city in Japan that relies completely on groundwater for drinking water. Groundwater in the Kumamoto region divided into shallow and deep aquifers. Around Lake Ezu, where one of Kumamoto City’s largest tap-water source wells are located, groundwater from both aquifers mixes, resulting in numerous springs. The aim of this study was to identify and quantify the relative contributions of the groundwater sources that discharge into Ezu Lake. River, lake, spring, and artesian well samples were collected every month between April 2021 and March 2022, and groundwater chemistry data for the shallow and deep aquifers were obtained from previous studies. The NO3− and SO42− concentrations indicated three end-members: (A) high NO3− from anthropogenic sources, (B) high SO42− from Shirakawa River water, and (C) low NO3− and SO42− from denitrification or dilution. Mixing analysis show 60–70% from A, 17–22% from B, and 7–25% from C for the lake waters. Also, the result showed that springs in the Kami-Ezu area were dominated by shallow aquifer water, whereas artesian wells in the Shimo-Ezu area reflected deep aquifer water. This is the first time that the contributions of groundwater sources in this area have been quantified using a three-component mixing approach. Furthermore, it was estimated that Shirakawa River infiltration, including the artificial recharge project from rice paddy, contributed approximately 57% to groundwater discharge into Ezu Lake in 2020. These results provide new insights into the contribution of artificial recharge from agricultural land to groundwater.