The Influence of Y2O3 Dosage on the Performance of Fe60/WC Laser Cladding Coating

To prepare a high-performance Fe-based laser cladding coating, herein, various Fe60/WC/Y<sub>2</sub>O<sub>3</sub> coatings are deposited on the surface of 42CrMo steel plate via a laser cladding technique. The WC dosage is fixed as 10 wt%, while the dosage of Y<sub>2</sub>O<sub>3</sub> ranges from 0 to 7.5 wt%. The influences of Y<sub>2</sub>O<sub>3</sub> dosage on the coating hardness, wear resistance, and corrosion resistance are investigated. With the addition of Y<sub>2</sub>O<sub>3</sub>, the feature peak of WC disappears, and the peaks of M<sub>23</sub>C<sub>6</sub> gradually weaken, indicating that Y<sub>2</sub>O<sub>3</sub> promotes the decomposition of WC and suppresses the formation of new metal carbides. When the dosage of Y<sub>2</sub>O<sub>3</sub> is 2.5 wt%, a grid-like structure is formed on the coating surface, suggesting uniform distribution of decomposed W within the Fe matrix. When the Y<sub>2</sub>O<sub>3</sub> dosage exceeds 5 wt%, a large amount of CO<sub>2</sub> gas is released, leading to an increase in surface pores. Through a comparison, the optimal dosage of Y<sub>2</sub>O<sub>3</sub> is 2.5 wt%, and the resulting 3# coating has the highest hardness of 861.97 HV. Moreover, the 3# coating also shows the minimum friction coefficient and the minimum wear volume, reflecting its superior wear resistance. The polished coating serves as a working electrode, and the corrosion resistance is tested in 3.5% NaCl solution. The sample containing 2.5 wt% Y<sub>2</sub>O<sub>3</sub> has the highest corrosion potential and the lowest corrosion current density, indicating excellent corrosion resistance. The enhanced performance is ascribed to the improved surface quality and the formation of a W-reinforced grid structure. The high-performance coating has promising application potential in material and component repair.

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Publication Details

Journal
Molecules
Published
2025-11-29
DOI
https://doi.org/10.3390/molecules30234598
Primary Topic
High Entropy Alloys Studies
Type
article
Field-Weighted Citation Impact
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The Influence of Y2O3 Dosage on the Performance of Fe60/WC Laser Cladding Coating

Xiaodong Hong, Dazhi Jiang, Chenguang Guo, Haiyan Jiang
Molecules
High Entropy Alloys Studies
article

The Influence of Y2O3 Dosage on the Performance of Fe60/WC Laser Cladding Coating

Xiaodong Hong, Dazhi Jiang, Chenguang Guo, Haiyan Jiang
article en

Abstract

To prepare a high-performance Fe-based laser cladding coating, herein, various Fe60/WC/Y<sub>2</sub>O<sub>3</sub> coatings are deposited on the surface of 42CrMo steel plate via a laser cladding technique. The WC dosage is fixed as 10 wt%, while the dosage of Y<sub>2</sub>O<sub>3</sub> ranges from 0 to 7.5 wt%. The influences of Y<sub>2</sub>O<sub>3</sub> dosage on the coating hardness, wear resistance, and corrosion resistance are investigated. With the addition of Y<sub>2</sub>O<sub>3</sub>, the feature peak of WC disappears, and the peaks of M<sub>23</sub>C<sub>6</sub> gradually weaken, indicating that Y<sub>2</sub>O<sub>3</sub> promotes the decomposition of WC and suppresses the formation of new metal carbides. When the dosage of Y<sub>2</sub>O<sub>3</sub> is 2.5 wt%, a grid-like structure is formed on the coating surface, suggesting uniform distribution of decomposed W within the Fe matrix. When the Y<sub>2</sub>O<sub>3</sub> dosage exceeds 5 wt%, a large amount of CO<sub>2</sub> gas is released, leading to an increase in surface pores. Through a comparison, the optimal dosage of Y<sub>2</sub>O<sub>3</sub> is 2.5 wt%, and the resulting 3# coating has the highest hardness of 861.97 HV. Moreover, the 3# coating also shows the minimum friction coefficient and the minimum wear volume, reflecting its superior wear resistance. The polished coating serves as a working electrode, and the corrosion resistance is tested in 3.5% NaCl solution. The sample containing 2.5 wt% Y<sub>2</sub>O<sub>3</sub> has the highest corrosion potential and the lowest corrosion current density, indicating excellent corrosion resistance. The enhanced performance is ascribed to the improved surface quality and the formation of a W-reinforced grid structure. The high-performance coating has promising application potential in material and component repair.

MoleculesVol. 30(23)
Foshan University (CN), Liaoning Technical University (CN)
Basic and Applied Basic Research Foundation of Guangdong Province
Openalex Percentile: Top 61%
High Entropy Alloys Studies
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