Multiscale Pore Structure and Heterogeneity of Deep Medium-Rank Coals in the Eastern Ordos Basin

The pore–fracture system in coal reservoirs is a critical factor controlling coalbed methane (CBM) productivity. This study focuses on deep coal samples from the Benxi and Taiyuan formations in the southeastern margin of the Ordos Basin. Using low-pressure CO2 and N2 adsorption experiments combined with fractal theory (Song and FHH models), the pore structure and heterogeneity of micropores (<2 nm) and mesopores (2–100 nm) were systematically analyzed. The results indicate that ash content is the primary inhibiting factor for pore development, showing significant negative correlations with micropore specific surface area, pore volume, and mesopore volume. The influence of macerals exhibits scale-dependent effects: vitrinite is the main contributor to micropore development, while vitrinite and ash content show a synergistic positive correlation with the volume proportion of 10–50 nm mesopores. Thermal maturity has no significant impact on pore volume but notably enhances mesopore heterogeneity. This study reveals an “ash-dominant, vitrinite-assisted” pore development pattern in low- to medium-rank coals, providing a theoretical basis for the efficient development of deep CBM.