Investigations on the cook-off response of GAP-based propellant under solid rocket motor structural constraints

GAP-based high-energy solid propellants are prone to ignition and explosion under accidental thermal stimuli during storage and use. This study investigates the cook-off response characteristics of GAP-based propellant under solid rocket motor structural constraints. A motor-representative experimental specimen that incorporates the structural constraints of a rocket motor was employed to conduct cook-off experiments. The complete response process of the propellant under motor-constrained conditions, i.e. from initial heating to final explosion, was captured using a high-speed laser schlieren imaging system. The study reveals that the GAP propellant-based motor response can be divided into several distinct stages: preheating, pyrolysis and gas generation, melting, ignition, convection combustion and potential deflagration-to-detonation transition (DDT). Furthermore, the influences of factors such as nozzle diameter, casing thickness, and heating flux density on the cook-off response behaviour were comprehensively investigated. Moreover, a two-dimensional transient numerical simulation model was developed, capable of representing the thermal decomposition, phase transition, ignition and rapid pressure rise processes of GAP-based propellant under thermal loading. The simulation results were validated against experimental data, showing <2 % deviation in ignition delay time and approximately 0.7 % difference in peak shock wave overpressure, demonstrating satisfactory predictive accuracy.

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Publication Details

Journal
Combustion and Flame
Published
2025-12-03
DOI
https://doi.org/10.1016/j.combustflame.2025.114683
Primary Topic
Energetic Materials and Combustion
Type
article
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article

Investigations on the cook-off response of GAP-based propellant under solid rocket motor structural constraints

Songlin Guo, Kang Hyeun Ji, Yi Wu, Mi Yan et al.
Combustion and Flame
Energetic Materials and Combustion
article

Investigations on the cook-off response of GAP-based propellant under solid rocket motor structural constraints

Songlin Guo, Kang Hyeun Ji, Yi Wu, Mi Yan, Xingyuan Wang, Qianlong Wang
article en

Abstract

GAP-based high-energy solid propellants are prone to ignition and explosion under accidental thermal stimuli during storage and use. This study investigates the cook-off response characteristics of GAP-based propellant under solid rocket motor structural constraints. A motor-representative experimental specimen that incorporates the structural constraints of a rocket motor was employed to conduct cook-off experiments. The complete response process of the propellant under motor-constrained conditions, i.e. from initial heating to final explosion, was captured using a high-speed laser schlieren imaging system. The study reveals that the GAP propellant-based motor response can be divided into several distinct stages: preheating, pyrolysis and gas generation, melting, ignition, convection combustion and potential deflagration-to-detonation transition (DDT). Furthermore, the influences of factors such as nozzle diameter, casing thickness, and heating flux density on the cook-off response behaviour were comprehensively investigated. Moreover, a two-dimensional transient numerical simulation model was developed, capable of representing the thermal decomposition, phase transition, ignition and rapid pressure rise processes of GAP-based propellant under thermal loading. The simulation results were validated against experimental data, showing <2 % deviation in ignition delay time and approximately 0.7 % difference in peak shock wave overpressure, demonstrating satisfactory predictive accuracy.

Combustion and FlameVol. 284
Beijing Institute of Technology (CN), Tianjin University (CN), Modern Electron (United States) (US)
Openalex Percentile: Top 57%
Energetic Materials and Combustion
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