Consecutive intra-particle phase transitions in the LiFePO <sub>4</sub> battery electrode material

When the asymmetry of the thermodynamic free energy of LiFePO 4 is accounted for, delithiation occurs through a solid solution pathway, thereby challenging the prevailing notion that this phase is only kinetically stabilized at the nano-scale.

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Publication Details

Journal
Journal of Materials Chemistry A
Published
2025-12-03
DOI
https://doi.org/10.1039/d5ta08057f
Primary Topic
Advancements in Battery Materials
Type
article
Field-Weighted Citation Impact
0.00
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article

Consecutive intra-particle phase transitions in the LiFePO 4 battery electrode material

Nana Ofori-Opoku, Daniel Brandell, Souzan Hammadi, Peter Broqvist
Journal of Materials Chemistry A
Advancements in Battery Materials
article

Consecutive intra-particle phase transitions in the LiFePO 4 battery electrode material

Nana Ofori-Opoku, Daniel Brandell, Souzan Hammadi, Peter Broqvist
article en

Abstract

When the asymmetry of the thermodynamic free energy of LiFePO 4 is accounted for, delithiation occurs through a solid solution pathway, thereby challenging the prevailing notion that this phase is only kinetically stabilized at the nano-scale.

Journal of Materials Chemistry AVol. 14(1)
Uppsala University (SE), Brockhouse Institute for Materials Research (CA), McMaster University (CA)
Openalex Percentile: Top 62%
Advancements in Battery Materials
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