Mechanism and Parameter Optimization of Surfactant-Assisted CO2 Huff-n-Puff for Enhanced Oil Recovery in Tight Conglomerate Reservoirs

China possesses abundant tight conglomerate oil resources. However, these reservoirs are typically characterized by low porosity and permeability, high clay mineral content, and complex pore structures, resulting in poor performance of conventional waterflooding development. Challenges including insufficient energy replenishment and high flow resistance ultimately lead to low oil recovery factors. This study systematically investigates surfactant-assisted CO2 huff-n-puff (SA-CO2-HnP) for enhanced oil recovery in tight conglomerate reservoirs. For a tight conglomerate reservoir in a Xinjiang block, a fully implicit, multiphase, multicomponent dual-porosity numerical model was established. By integrating pore–throat distributions acquired through high-pressure mercury intrusion with a self-developed MATLAB PVT package, nanoconfinement-induced shifts in the phase envelope were rigorously embedded into the simulation framework. The calibrated model was subsequently employed to conduct a comprehensive sensitivity analysis, quantitatively delineating the influence of petrophysical, completion, and operational variables on production performance. Simulation results demonstrate that compared to conventional CO2 huff-n-puff, the addition of surfactants increases the cumulative recovery factor by 3.5 percentage points over a 20-year production period. The enhancement mechanisms primarily include reducing CO2–oil interfacial tension (IFT) and minimum miscibility pressure (MMP), improving reservoir wettability, and promoting CO2 dissolution and diffusion in crude oil. Sensitivity analysis reveals that injection duration, injection pressure, and injection rate significantly influence recovery efficiency, while soaking time exhibits relatively limited impact. Moreover, an optimal surfactant concentration (0.0003 mole fraction) exists; excessive concentrations lead to diminished enhancement effects due to competitive adsorption and pore blockage. This study demonstrates that SA-CO2-HnP technology offers favorable economic viability and operational feasibility, providing theoretical foundation and parameter optimization guidance for efficient tight conglomerate oil reservoir development.

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Journal
Processes
Published
2025-12-02
DOI
https://doi.org/10.3390/pr13123888
Primary Topic
Enhanced Oil Recovery Techniques
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article
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article

Mechanism and Parameter Optimization of Surfactant-Assisted CO2 Huff-n-Puff for Enhanced Oil Recovery in Tight Conglomerate Reservoirs

Guoshan Zhang, Ming Li, Mingjian Wang, Jiaxing Liu et al.
Processes
Enhanced Oil Recovery Techniques
article

Mechanism and Parameter Optimization of Surfactant-Assisted CO2 Huff-n-Puff for Enhanced Oil Recovery in Tight Conglomerate Reservoirs

Guoshan Zhang, Ming Li, Mingjian Wang, Jiaxing Liu, Menɡ Ninɡ, Lei Li, Yong Zhao, Jigang Zhang
article en

Abstract

China possesses abundant tight conglomerate oil resources. However, these reservoirs are typically characterized by low porosity and permeability, high clay mineral content, and complex pore structures, resulting in poor performance of conventional waterflooding development. Challenges including insufficient energy replenishment and high flow resistance ultimately lead to low oil recovery factors. This study systematically investigates surfactant-assisted CO2 huff-n-puff (SA-CO2-HnP) for enhanced oil recovery in tight conglomerate reservoirs. For a tight conglomerate reservoir in a Xinjiang block, a fully implicit, multiphase, multicomponent dual-porosity numerical model was established. By integrating pore–throat distributions acquired through high-pressure mercury intrusion with a self-developed MATLAB PVT package, nanoconfinement-induced shifts in the phase envelope were rigorously embedded into the simulation framework. The calibrated model was subsequently employed to conduct a comprehensive sensitivity analysis, quantitatively delineating the influence of petrophysical, completion, and operational variables on production performance. Simulation results demonstrate that compared to conventional CO2 huff-n-puff, the addition of surfactants increases the cumulative recovery factor by 3.5 percentage points over a 20-year production period. The enhancement mechanisms primarily include reducing CO2–oil interfacial tension (IFT) and minimum miscibility pressure (MMP), improving reservoir wettability, and promoting CO2 dissolution and diffusion in crude oil. Sensitivity analysis reveals that injection duration, injection pressure, and injection rate significantly influence recovery efficiency, while soaking time exhibits relatively limited impact. Moreover, an optimal surfactant concentration (0.0003 mole fraction) exists; excessive concentrations lead to diminished enhancement effects due to competitive adsorption and pore blockage. This study demonstrates that SA-CO2-HnP technology offers favorable economic viability and operational feasibility, providing theoretical foundation and parameter optimization guidance for efficient tight conglomerate oil reservoir development.

ProcessesVol. 13(12)
Research Institute of Petroleum Exploration and Development (CN), China University of Petroleum, East China (CN)
National Key Research and Development Program of China
Openalex Percentile: Top 53%
Enhanced Oil Recovery Techniques
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