Exploring chromium oxynitrides as efficient catalysts for the water-gas shift reaction
Transition metal nitrides and oxynitrides exhibit catalytic properties that make them promising candidates as alternatives to noble metals. A series of high-surface-area chromium oxynitrides, CrO x N 1-x (0.10 < x < 0.25), was synthesized from a cheap hydroxide precursor and investigated as unconventional heterogeneous catalysts for the Water-Gas Shift (WGS) reaction. Currently, this reaction is predominantly catalyzed by platinum. Replacing platinum with chromium oxynitrides could provide a more cost-effective and environmentally friendly solution. A series of high surface area chromium oxynitrides CrO x N 1-x (0.10 < x < 0.25) was synthesized from a hydroxide precursor and evaluated as a potential alternative to noble metal-based heterogeneous catalysts for the water-gas shift (WGS) reaction.
Authors
- Fabien Grasset (ORCID: https://orcid.org/0000-0002-4911-0214)
- Franck Tessier (ORCID: https://orcid.org/0000-0002-1253-7011)
- Stéphane Cordier (ORCID: https://orcid.org/0000-0003-0707-3774)
- Guillaume Dubois (ORCID: https://orcid.org/0009-0009-5282-7361)
- Sébastien MATHIVET
Institutions
- Centre National de la Recherche Scientifique (FR)
- National Institute for Materials Science (JP)
- Institut des Sciences Chimiques de Rennes (FR)
- Université de Rennes (FR)
Publication Details
- Journal
- Solid State Sciences
- Published
- 2025-12-02
- DOI
- https://doi.org/10.1016/j.solidstatesciences.2025.108154
- Primary Topic
- Inorganic Chemistry and Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00