Exploring chromium oxynitrides as efficient catalysts for the water-gas shift reaction

Transition metal nitrides and oxynitrides exhibit catalytic properties that make them promising candidates as alternatives to noble metals. A series of high-surface-area chromium oxynitrides, CrO x N 1-x (0.10 < x < 0.25), was synthesized from a cheap hydroxide precursor and investigated as unconventional heterogeneous catalysts for the Water-Gas Shift (WGS) reaction. Currently, this reaction is predominantly catalyzed by platinum. Replacing platinum with chromium oxynitrides could provide a more cost-effective and environmentally friendly solution. A series of high surface area chromium oxynitrides CrO x N 1-x (0.10 < x < 0.25) was synthesized from a hydroxide precursor and evaluated as a potential alternative to noble metal-based heterogeneous catalysts for the water-gas shift (WGS) reaction.

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Publication Details

Journal
Solid State Sciences
Published
2025-12-02
DOI
https://doi.org/10.1016/j.solidstatesciences.2025.108154
Primary Topic
Inorganic Chemistry and Materials
Type
article
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Exploring chromium oxynitrides as efficient catalysts for the water-gas shift reaction

Fabien Grasset, Franck Tessier, Stéphane Cordier, Guillaume Dubois et al.
Solid State Sciences
Inorganic Chemistry and Materials
article

Exploring chromium oxynitrides as efficient catalysts for the water-gas shift reaction

Fabien Grasset, Franck Tessier, Stéphane Cordier, Guillaume Dubois, Sébastien MATHIVET
article en

Abstract

Transition metal nitrides and oxynitrides exhibit catalytic properties that make them promising candidates as alternatives to noble metals. A series of high-surface-area chromium oxynitrides, CrO x N 1-x (0.10 < x < 0.25), was synthesized from a cheap hydroxide precursor and investigated as unconventional heterogeneous catalysts for the Water-Gas Shift (WGS) reaction. Currently, this reaction is predominantly catalyzed by platinum. Replacing platinum with chromium oxynitrides could provide a more cost-effective and environmentally friendly solution. A series of high surface area chromium oxynitrides CrO x N 1-x (0.10 < x < 0.25) was synthesized from a hydroxide precursor and evaluated as a potential alternative to noble metal-based heterogeneous catalysts for the water-gas shift (WGS) reaction.

Solid State SciencesVol. 172
Centre National de la Recherche Scientifique (FR), National Institute for Materials Science (JP), Institut des Sciences Chimiques de Rennes (FR), Université de Rennes (FR)
Openalex Percentile: Top 68%
Inorganic Chemistry and Materials
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