Electrochemical Approaches For Barbier‐Like Carbon–Carbon Bond Formations: Cases of Allylations and Propargylations

ABSTRACT Formation of carbon–carbon bonds is the main tool for building skeletons of organic compounds. This review article endeavors primarily toward the development of sustainable synthetic tactics to build up new carbon–carbon bonds by electrochemical approaches. During the electrochemical formation of carbon–carbon bonds, Barbier‐like addition protocols are only included in the review. Among the Barbier‐like reactions, the addition of allylic and propargylic moieties to the different electrophilic centers is incorporated. These electrochemical processes have several obvious advantages, including simplicity, effectiveness, and environmental friendliness.