Optical conductivity study of mixed-valent quasi-one-dimensional <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>CeIr</mml:mi> <mml:mn>3</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">B</mml:mi> <

We present a combined theoretical and experimental study on the optical conductivity of ${\mathrm{CeIr}}_{3}{\mathrm{B}}_{2}$, where quasi-one-dimensional Ce chains form along the $c$ axis of the monoclinic crystal. Significant hybridization-induced features are observed along the Ce chains by broadband infrared spectroscopy, demonstrating mixed-valent behavior over a wide range of temperatures (6--300 K) and energies (up to 0.8 eV). The ferromagnetic transition at 41 K had no noticeable influence on the temperature evolution of the optical conductivity. A comparison with density functional theory plus dynamic mean-field theory calculations demonstrates the quasi-one-dimensional nature of ${\mathrm{CeIr}}_{3}{\mathrm{B}}_{2}$ and the local character of the interactions responsible for the electronic renormalization. Furthermore, we demonstrate how the spectroscopic signatures of this mixed-valent compound are captured by theory, providing a clear distinction from the response expected in the integer-valent Kondo regime.

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Journal
Physical review. B./Physical review. B
Published
2025-12-01
DOI
https://doi.org/10.1103/tc7y-872m
Primary Topic
Rare-earth and actinide compounds
Type
article
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Optical conductivity study of mixed-valent quasi-one-dimensional <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>CeIr</mml:mi> <mml:mn>3</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">B</mml:mi> <

Rohit P. Prasankumar, Eric D. Bauer, Christopher C. Homes, Thomas U. Böhm et al.
Physical review. B./Physical review. B
Rare-earth and actinide compounds
article

Optical conductivity study of mixed-valent quasi-one-dimensional <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>CeIr</mml:mi> <mml:mn>3</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">B</mml:mi> <

Rohit P. Prasankumar, Eric D. Bauer, Christopher C. Homes, Thomas U. Böhm, Yu Liu, Kenneth R. O’Neal, Bo Gyu Jang, F. Ronning, Jian‐Xin Zhu, Nicholas Sirica
article en

Abstract

We present a combined theoretical and experimental study on the optical conductivity of ${\mathrm{CeIr}}_{3}{\mathrm{B}}_{2}$, where quasi-one-dimensional Ce chains form along the $c$ axis of the monoclinic crystal. Significant hybridization-induced features are observed along the Ce chains by broadband infrared spectroscopy, demonstrating mixed-valent behavior over a wide range of temperatures (6--300 K) and energies (up to 0.8 eV). The ferromagnetic transition at 41 K had no noticeable influence on the temperature evolution of the optical conductivity. A comparison with density functional theory plus dynamic mean-field theory calculations demonstrates the quasi-one-dimensional nature of ${\mathrm{CeIr}}_{3}{\mathrm{B}}_{2}$ and the local character of the interactions responsible for the electronic renormalization. Furthermore, we demonstrate how the spectroscopic signatures of this mixed-valent compound are captured by theory, providing a clear distinction from the response expected in the integer-valent Kondo regime.

Physical review. B./Physical review. BVol. 112(23)
United States Naval Research Laboratory (US), Los Alamos National Laboratory (US), Brookhaven National Laboratory (US), Leibniz Institute for Solid State and Materials Research (DE), Kyung Hee University (KR), Center for Integrated Nanotechnologies (US), Roberts Enterprise Development Fund (US), Intellectual Ventures (United States) (US), United States Navy (US)
Openalex Percentile: Top 76%
Rare-earth and actinide compounds
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