Optical conductivity study of mixed-valent quasi-one-dimensional <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>CeIr</mml:mi> <mml:mn>3</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">B</mml:mi> <
We present a combined theoretical and experimental study on the optical conductivity of ${\mathrm{CeIr}}_{3}{\mathrm{B}}_{2}$, where quasi-one-dimensional Ce chains form along the $c$ axis of the monoclinic crystal. Significant hybridization-induced features are observed along the Ce chains by broadband infrared spectroscopy, demonstrating mixed-valent behavior over a wide range of temperatures (6--300 K) and energies (up to 0.8 eV). The ferromagnetic transition at 41 K had no noticeable influence on the temperature evolution of the optical conductivity. A comparison with density functional theory plus dynamic mean-field theory calculations demonstrates the quasi-one-dimensional nature of ${\mathrm{CeIr}}_{3}{\mathrm{B}}_{2}$ and the local character of the interactions responsible for the electronic renormalization. Furthermore, we demonstrate how the spectroscopic signatures of this mixed-valent compound are captured by theory, providing a clear distinction from the response expected in the integer-valent Kondo regime.
Authors
- Rohit P. Prasankumar (ORCID: https://orcid.org/0000-0003-0902-2831)
- Eric D. Bauer (ORCID: https://orcid.org/0000-0003-0017-1937)
- Christopher C. Homes (ORCID: https://orcid.org/0000-0001-7087-756X)
- Thomas U. Böhm (ORCID: https://orcid.org/0000-0001-5525-8592)
- Yu Liu (ORCID: https://orcid.org/0000-0001-8886-2876)
- Kenneth R. O’Neal (ORCID: https://orcid.org/0000-0001-9149-1957)
- Bo Gyu Jang (ORCID: https://orcid.org/0000-0002-9299-6241)
- F. Ronning (ORCID: https://orcid.org/0000-0002-2679-7957)
- Jian‐Xin Zhu (ORCID: https://orcid.org/0000-0001-7991-3918)
- Nicholas Sirica (ORCID: https://orcid.org/0000-0002-3265-4186)
Institutions
- United States Naval Research Laboratory (US)
- Los Alamos National Laboratory (US)
- Brookhaven National Laboratory (US)
- Leibniz Institute for Solid State and Materials Research (DE)
- Kyung Hee University (KR)
- Center for Integrated Nanotechnologies (US)
- Roberts Enterprise Development Fund (US)
- Intellectual Ventures (United States) (US)
- United States Navy (US)
Publication Details
- Journal
- Physical review. B./Physical review. B
- Published
- 2025-12-01
- DOI
- https://doi.org/10.1103/tc7y-872m
- Primary Topic
- Rare-earth and actinide compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00