A stable amino-functionalized fluorinated metal–organic framework for efficient separation of propyne/propylene
The separation of propylene (C<sub>3</sub>H<sub>6</sub>) is important in industry. Here, we report a highly stable fluorinated metal-organic framework, TNU-DPA-1. With a suitable pore size and abundant binding sites, it shows excellent C<sub>3</sub>H<sub>4</sub>/C<sub>3</sub>H<sub>6</sub> separation performance. In a dynamic breakthrough experiment, a total of 19.6 mmol g<sup>-1</sup> of C<sub>3</sub>H<sub>6</sub> with 99.99% purity was obtained.
Authors
- Cheng‐Peng Li (ORCID: https://orcid.org/0000-0002-6798-9541)
- Zhengyi Di (ORCID: https://orcid.org/0000-0001-9770-4044)
- Xiaorong Zhao (ORCID: https://orcid.org/0000-0001-7392-2549)
- Beibei Li (ORCID: https://orcid.org/0000-0002-9448-483X)
- Yun‐Tao Huang (ORCID: https://orcid.org/0000-0001-6669-7494)
- Zhigang Song (ORCID: https://orcid.org/0000-0002-4383-2662)
Institutions
- Tianjin Normal University (CN)
- Henan University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-12-01
- DOI
- https://doi.org/10.1039/d5cc05733g
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00