Atomic zinc active sites on imine-pyridine based covalent organic frameworks for enhancing photocatalytic H <sub>2</sub> O <sub>2</sub> production

Atomically dispersed metal sites were immobilized on imine-pyridine based covalent organic frameworks to explore their novel applications in simulated sunlight-driven H<sub>2</sub>O<sub>2</sub> production. Among them, Zn-COF<sub>TAPB-BPA</sub> achieved a high H<sub>2</sub>O<sub>2</sub> evolution rate of 2998 µmol g<sup>-1</sup> h<sup>-1</sup> and an apparent quantum yield (AQY) of 4.17% at 450 nm in pure water.

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Publication Details

Journal
Chemical Communications
Published
2025-12-01
DOI
https://doi.org/10.1039/d5cc05126f
Primary Topic
Covalent Organic Framework Applications
Type
article
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article

Atomic zinc active sites on imine-pyridine based covalent organic frameworks for enhancing photocatalytic H 2 O 2 production

Xuan‐He Liu, Bing Sun, Rongfu Huang
Chemical Communications
Covalent Organic Framework Applications
article

Atomic zinc active sites on imine-pyridine based covalent organic frameworks for enhancing photocatalytic H 2 O 2 production

Xuan‐He Liu, Bing Sun, Rongfu Huang
article en

Abstract

Atomically dispersed metal sites were immobilized on imine-pyridine based covalent organic frameworks to explore their novel applications in simulated sunlight-driven H<sub>2</sub>O<sub>2</sub> production. Among them, Zn-COF<sub>TAPB-BPA</sub> achieved a high H<sub>2</sub>O<sub>2</sub> evolution rate of 2998 µmol g<sup>-1</sup> h<sup>-1</sup> and an apparent quantum yield (AQY) of 4.17% at 450 nm in pure water.

Chemical CommunicationsVol. 62(2)
Huanggang Normal University (CN), China University of Geosciences (Beijing) (CN), Hubei Normal University (CN)
Openalex Percentile: Top 69%
Covalent Organic Framework Applications
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Atomic zinc active sites on imine-pyridine based covalent organic frameworks for enhancing photocatalytic H <sub>2</sub> O <sub>2</sub> production — Xuan‐He Liu, Bing Sun, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS