Blue-light assisted transformation of CS and PS bonds of thioamides and thiophosphonyl diamides into CN and PN bonds of <i>N</i> -sulfonyl amidines <i>via</i> interaction with iminoiodinanes

An azide-free approach toward N -sulfonyl amidines, including phosphorus-containing derivatives based on the reactions of thioamides and thiophosphonyl diamides with iminoiodinanes, was developed.

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Publication Details

Journal
New Journal of Chemistry
Published
2025-11-29
DOI
https://doi.org/10.1039/d5nj03889h
Primary Topic
Radical Photochemical Reactions
Type
article
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article

Blue-light assisted transformation of CS and PS bonds of thioamides and thiophosphonyl diamides into CN and PN bonds of N -sulfonyl amidines via interaction with iminoiodinanes

Tetyana Beryozkina, Павел А. Слепухин, Vladimir G. Ilkin, Wim Dehaen et al.
New Journal of Chemistry
Radical Photochemical Reactions
article

Blue-light assisted transformation of CS and PS bonds of thioamides and thiophosphonyl diamides into CN and PN bonds of N -sulfonyl amidines via interaction with iminoiodinanes

Tetyana Beryozkina, Павел А. Слепухин, Vladimir G. Ilkin, Wim Dehaen, Николай А. Беляев, А.Д. Никулин, Vasiliy А. Bakulev, P. S. Silaichev, Valeriy O. Filimonov
article en

Abstract

An azide-free approach toward N -sulfonyl amidines, including phosphorus-containing derivatives based on the reactions of thioamides and thiophosphonyl diamides with iminoiodinanes, was developed.

New Journal of ChemistryVol. 50(2)
Perm State University (RU), Ural Federal University (RU), Institute of Organic Synthesis (RU), Ural Branch of the Russian Academy of Sciences (RU), KU Leuven (BE)
Openalex Percentile: Top 72%
Radical Photochemical Reactions
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