Focused Sampling for Low-Cost and Accurate Ehrenfest Modeling of Cavity Quantum Electrodynamics
An economic modeling approach for cavity quantum electrodynamics is provided by mean-field dynamics, wherein the optical field is described classically while a self-consistent interaction with quantum emitters is incorporated through the Ehrenfest theorem. However, conventional implementations of mean-field dynamics are known to suffer from a catastrophic leakage of zero-point energy, to lose accuracy in the short-cavity limit, and to require large numbers of trajectories to be sampled. Here, we address these three shortcomings within a single integrated approach. This approach builds on our recently proposed modification of the Ehrenfest theorem, referred to as decoupled mean-field (DC-MF) dynamics, in combination with a focused sampling scheme that enforces zero-point energy at the single-trajectory level. The approach is shown to yield high accuracy in both short and long-cavity limits while reaching convergence within a minimal amount of trajectories.
Authors
- Alex Krotz (ORCID: https://orcid.org/0000-0001-8189-7902)
- Ming‐Hsiu Hsieh (ORCID: https://orcid.org/0000-0003-2098-1304)
- Roel Tempelaar (ORCID: https://orcid.org/0000-0003-0786-7304)
Institutions
- Northwestern University (US)
Publication Details
- Journal
- Journal of Chemical Theory and Computation
- Published
- 2025-11-28
- DOI
- https://doi.org/10.1021/acs.jctc.5c01639
- Citations
- 1
- Primary Topic
- Quantum Information and Cryptography
- Type
- article
- Field-Weighted Citation Impact
- 2.48