Focused Sampling for Low-Cost and Accurate Ehrenfest Modeling of Cavity Quantum Electrodynamics

An economic modeling approach for cavity quantum electrodynamics is provided by mean-field dynamics, wherein the optical field is described classically while a self-consistent interaction with quantum emitters is incorporated through the Ehrenfest theorem. However, conventional implementations of mean-field dynamics are known to suffer from a catastrophic leakage of zero-point energy, to lose accuracy in the short-cavity limit, and to require large numbers of trajectories to be sampled. Here, we address these three shortcomings within a single integrated approach. This approach builds on our recently proposed modification of the Ehrenfest theorem, referred to as decoupled mean-field (DC-MF) dynamics, in combination with a focused sampling scheme that enforces zero-point energy at the single-trajectory level. The approach is shown to yield high accuracy in both short and long-cavity limits while reaching convergence within a minimal amount of trajectories.

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Publication Details

Journal
Journal of Chemical Theory and Computation
Published
2025-11-28
DOI
https://doi.org/10.1021/acs.jctc.5c01639
Citations
1
Primary Topic
Quantum Information and Cryptography
Type
article
Field-Weighted Citation Impact
2.48
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article

Focused Sampling for Low-Cost and Accurate Ehrenfest Modeling of Cavity Quantum Electrodynamics

Alex Krotz, Ming‐Hsiu Hsieh, Roel Tempelaar
1 citations
Journal of Chemical Theory and Computation
Quantum Information and Cryptography
2.48
article

Focused Sampling for Low-Cost and Accurate Ehrenfest Modeling of Cavity Quantum Electrodynamics

Alex Krotz, Ming‐Hsiu Hsieh, Roel Tempelaar
article en
1 citations

Abstract

An economic modeling approach for cavity quantum electrodynamics is provided by mean-field dynamics, wherein the optical field is described classically while a self-consistent interaction with quantum emitters is incorporated through the Ehrenfest theorem. However, conventional implementations of mean-field dynamics are known to suffer from a catastrophic leakage of zero-point energy, to lose accuracy in the short-cavity limit, and to require large numbers of trajectories to be sampled. Here, we address these three shortcomings within a single integrated approach. This approach builds on our recently proposed modification of the Ehrenfest theorem, referred to as decoupled mean-field (DC-MF) dynamics, in combination with a focused sampling scheme that enforces zero-point energy at the single-trajectory level. The approach is shown to yield high accuracy in both short and long-cavity limits while reaching convergence within a minimal amount of trajectories.

Journal of Chemical Theory and ComputationVol. 21(23)
Northwestern University (US)
Openalex Percentile: Top 8%
Quantum Information and Cryptography
2.48
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Focused Sampling for Low-Cost and Accurate Ehrenfest Modeling of Cavity Quantum Electrodynamics — Alex Krotz, Ming‐Hsiu Hsieh, et al. · Journal of Chemical Theory and Computation (2025) | TGRS Research Map | TGRS