Blending portland limestone cement with supplementary cementitious materials to minimize clinker content

Portland limestone cements (PLCs) have become increasingly prevalent in concrete production in the U.S. and Europe. This study evaluated cement hydration, workability and compressive strength development of blended binders for concrete produced with PLC (15 wt% limestone) and calcined clay, Class F fly ash, pumice or perlite supplementary cementitious materials (SCMs). The goal of the study was to investigate cement-SCM blends for the US market that are similar in composition to Limestone Calcined Clay Cement (LC 3 ) binders using readily-available cements and SCMs in the U.S. Blending SCMs with PLCs changed workability, with calcined clay having a greater impact on workability than the other SCMs. Compressive strengths also were as expected for SCM blends and were somewhat lower in the PLC mortars compared to ordinary portland cement mortars. Similar carboaluminate reaction products were identified when using fly ash or a calcined kaolinitic clay, suggesting that synergies from combining cement, limestone and calcined clays are not limited to this SCM type. The use of local SCMs with PLCs is ready for implementation and allows for clinker replacement levels near that of LC 3 , while achieving similar performance. • Workability changes in SCM-containing blended cements produced with PLC. • Comparable AFm phased identified in fly ash +PLC to those observed in LC3. • Use of PLCs lead to slight reduction on compressive strength. • Fly ash or natural pozzolans can achieve similar effects to those reported for LC3.

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Publication Details

Journal
Construction and Building Materials
Published
2025-11-28
DOI
https://doi.org/10.1016/j.conbuildmat.2025.144657
Primary Topic
Concrete and Cement Materials Research
Type
article
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article

Blending portland limestone cement with supplementary cementitious materials to minimize clinker content

Susan A. Bernal, Maria Juenger, Katey O’Quinn
Construction and Building Materials
Concrete and Cement Materials Research
article

Blending portland limestone cement with supplementary cementitious materials to minimize clinker content

Susan A. Bernal, Maria Juenger, Katey O’Quinn
article en

Abstract

Portland limestone cements (PLCs) have become increasingly prevalent in concrete production in the U.S. and Europe. This study evaluated cement hydration, workability and compressive strength development of blended binders for concrete produced with PLC (15 wt% limestone) and calcined clay, Class F fly ash, pumice or perlite supplementary cementitious materials (SCMs). The goal of the study was to investigate cement-SCM blends for the US market that are similar in composition to Limestone Calcined Clay Cement (LC 3 ) binders using readily-available cements and SCMs in the U.S. Blending SCMs with PLCs changed workability, with calcined clay having a greater impact on workability than the other SCMs. Compressive strengths also were as expected for SCM blends and were somewhat lower in the PLC mortars compared to ordinary portland cement mortars. Similar carboaluminate reaction products were identified when using fly ash or a calcined kaolinitic clay, suggesting that synergies from combining cement, limestone and calcined clays are not limited to this SCM type. The use of local SCMs with PLCs is ready for implementation and allows for clinker replacement levels near that of LC 3 , while achieving similar performance. • Workability changes in SCM-containing blended cements produced with PLC. • Comparable AFm phased identified in fly ash +PLC to those observed in LC3. • Use of PLCs lead to slight reduction on compressive strength. • Fly ash or natural pozzolans can achieve similar effects to those reported for LC3.

Construction and Building MaterialsVol. 505
Openalex Percentile: Top 62%
Concrete and Cement Materials Research
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