Nanostructured Oxides Obtained by Anodizing Aluminum Intermetallic Alloys

Aluminum anodizing has been a well-established method of corrosion protection for over a century. A nanoporous and hexagonally arranged anodic aluminum oxide has become one of the most important template materials in nanotechnology. A totally new branch of research in anodizing was sparked by purple gold anodizing. This pioneering research showed that metal aluminides can be anodized and result in new classes of nanomaterials. Simultaneously, materials from Ti-Al systems were anodized, and the transition from nanopores to the nanotubes was mechanistically understood. Also, materials like Ni₃Al were anodized; however, the most frequently used aluminides are materials from the Fe-Al binary phase diagram, from Fe₃Al to FeAl₃. The research on metal aluminides has shown that it is possible to obtain mixed oxides with a highly developed nanostructured morphology. A significant amount of fundamental research has shown it is possible to obtain such mixed oxides with tunable band gaps, depending on the substrate material, anodizing conditions, and heat treatment. Despite significant progress in fundamental research, there is a noticeable lack of applied research on this class of materials.