Printability Metrics and Strain Rate Sensitivity of Multirole PVDF in Extrusion-Based Additive Manufacturing

Recently, significant attention has been paid to the use of multirole materials in additive manufacturing (AM). Polyvinylidene fluoride (PVDF) is an ideal candidate material that has been selected for examination because of its unique characteristics. This study establishes a correlation between the macroscopic mechanical behavior and microscopic structural mechanisms, enabling the utilization of the deformation rate in tailoring the mechanical response of printed PVDF components. This research focuses on testing AM PVDF samples under different strain rates (10-300 mm/min), aiming to report their behavior under loading conditions compatible with the stochastic nature of real-life applications. The thermal (thermogravimetric analysis and differential scanning calorimetry) and rheological (viscosity and melt flow rate) properties were investigated along with their morphological characteristics (scanning electron microscopy). The response under combined dynamic and thermal loading was investigated through dynamic mechanical analysis, and the structural characteristics were investigated using spectroscopic techniques (Raman and energy-dispersive spectroscopy). The properties examined were the ultimate and yield strengths, modulus of elasticity, and toughness. Sensitivity index data are also provided. For completeness, the flexural strength, Charpy impact strength, and Vickers hardness were also evaluated, suggesting that the AM PVDF samples exhibit a resilient nature even when subjected to extremes regarding their strain rate versus their overall mechanical characteristics. PVDF exhibited a strain-hardening response with an increase in its strength of up to ~25% (300 mm/min) and a stiffness of ~15% (100 mm/min) as the loading speed of testing increased.