Organosulfur‐Rich Porous Carbon Cathode Enables Soluble‐Polysulfide‐Free and High‐Rate Potassium‐Sulfur Batteries

Potassium-sulfur (K-S) batteries are emerging as one of the most promising candidates for next-generation energy storage, owing to their high energy density and cost-effectiveness. However, the severe polysulfide shuttle effect and sluggish redox kinetics of sulfur cathodes remain critical barriers to their practical application. Herein, a class of organosulfur-rich porous carbon (OSPC) has been developed as a high-performance cathode for soluble-polysulfide-free and high-rate K-S batteries. The as-constructed OSPC achieves molecular-scale confinement of sulfur species within the carbon skeleton via covalent bonding, which enables solid-solid sulfur redox pathways without generation of electrolyte-soluble polysulfides. Moreover, the conductive carbon skeleton of OSPC with well-developed porosity can facilitate potassium ion and electron transport within the bulk cathode and significantly improve sulfur redox kinetics. Benefiting from these integrated merits, excellent high rate capability (240.8 mAh g^-1 at 5 A g^-1 based on the mass of OSPC), long-term cycling stability (77% retention after 500 cycles at 5 A g^-1), and remarkable areal capacity (4.5 mAh cm^-2) can be achieved for the OSPC cathodes. Additionally, the feasibility of synthesizing OSPC from real-world waste plastics is demonstrated, which offers a dual benefit of alleviating plastic pollution and enabling the fabrication of low-cost yet high-performance cathodes for K-S batteries.