Corrosion Behavior of Inconel 625 Overlay and N‐Containing Nickel‐Based Overlay in Molten LiF‐NaF‐KF

ABSTRACT To address nickel deficiency, inspired by high‐nitrogen steel, this study replaced Ni with N. Based on Inconel 625, five N‐containing nickel‐based flux‐cored wires were designed and prepared. These, along with Inconel 625 wire, were used to create overlays via MIG/MAG welding. Hot corrosion tests in LiF+NaF+KF molten salt at 600°C showed the N‐containing overlay's weight loss was at least 0.401 mg/mm 2 , significantly lower than Inconel 625's 0.483 mg/mm 2 . XRD, SEM, and EDS revealed identical corrosion products (NiCr 2 O 4 , Cr 2 O 3 , FeCr 2 O 4 , and NiO). XPS indicated the N‐containing overlay had more protective, dense Cr 2 O 3 , while Inconel 625 formed more porous NiO. Thus, the N‐containing overlay exhibits superior FLiNaK salt corrosion resistance.

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Publication Details

Journal
Materials and Corrosion
Published
2025-11-27
DOI
https://doi.org/10.1002/maco.70074
Primary Topic
Molten salt chemistry and electrochemical processes
Type
article
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article

Corrosion Behavior of Inconel 625 Overlay and N‐Containing Nickel‐Based Overlay in Molten LiF‐NaF‐KF

Taisen Yang, Y.L. Su, Yu Tian, Shuo Feng et al.
Materials and Corrosion
Molten salt chemistry and electrochemical processes
article

Corrosion Behavior of Inconel 625 Overlay and N‐Containing Nickel‐Based Overlay in Molten LiF‐NaF‐KF

Taisen Yang, Y.L. Su, Yu Tian, Shuo Feng, Zhixin Yang
article en

Abstract

ABSTRACT To address nickel deficiency, inspired by high‐nitrogen steel, this study replaced Ni with N. Based on Inconel 625, five N‐containing nickel‐based flux‐cored wires were designed and prepared. These, along with Inconel 625 wire, were used to create overlays via MIG/MAG welding. Hot corrosion tests in LiF+NaF+KF molten salt at 600°C showed the N‐containing overlay's weight loss was at least 0.401 mg/mm 2 , significantly lower than Inconel 625's 0.483 mg/mm 2 . XRD, SEM, and EDS revealed identical corrosion products (NiCr 2 O 4 , Cr 2 O 3 , FeCr 2 O 4 , and NiO). XPS indicated the N‐containing overlay had more protective, dense Cr 2 O 3 , while Inconel 625 formed more porous NiO. Thus, the N‐containing overlay exhibits superior FLiNaK salt corrosion resistance.

Materials and Corrosion
Shenyang University of Technology (CN), China Special Equipment Inspection and Research Institute (CN), Second Hospital of Liaohe Oilfield (CN), Pingjin Hospital (CN)
Openalex Percentile: Top 66%
Molten salt chemistry and electrochemical processes
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