Influence of infill geometry on the degradation performance of 3D printed TiO2 photocatalytic filters

In this study, TiO 2 filters with complex geometries (i.e., grid, honeycomb and gyroid) were 3D printed via direct ink writing (DIW), sintered at 1350°C, coated using a sol-gel method and treated at 600°C to induce the formation of anatase-phase TiO 2 . The sintered TiO 2 filters exhibited a relative density between 92.19 % and 94.81%, with shrinkage ranging from 19% to 22%. XRD and SEM analyses confirmed the formation of the anatase phase and a uniform coating with a thickness of 4.3-4.5 μm on the TiO 2 filters. The surface-engineered TiO 2 filters were evaluated for the photocatalytic degradation of Rhodamine B under UV light. Among the tested structures, the gyroid geometry exhibited the highest performance (completely degrading Rhodamine B in 200 minutes) due to its higher surface area.

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Publication Details

Journal
Ceramics International
Published
2025-11-26
DOI
https://doi.org/10.1016/j.ceramint.2025.11.372
Primary Topic
TiO2 Photocatalysis and Solar Cells
Type
article
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article

Influence of infill geometry on the degradation performance of 3D printed TiO2 photocatalytic filters

Claudia Mazzuca, F. Nanni, Mario Bragaglia, Marco Mariani et al.
Ceramics International
TiO2 Photocatalysis and Solar Cells
article

Influence of infill geometry on the degradation performance of 3D printed TiO2 photocatalytic filters

Claudia Mazzuca, F. Nanni, Mario Bragaglia, Marco Mariani, Jyoti Kumari
article en

Abstract

In this study, TiO 2 filters with complex geometries (i.e., grid, honeycomb and gyroid) were 3D printed via direct ink writing (DIW), sintered at 1350°C, coated using a sol-gel method and treated at 600°C to induce the formation of anatase-phase TiO 2 . The sintered TiO 2 filters exhibited a relative density between 92.19 % and 94.81%, with shrinkage ranging from 19% to 22%. XRD and SEM analyses confirmed the formation of the anatase phase and a uniform coating with a thickness of 4.3-4.5 μm on the TiO 2 filters. The surface-engineered TiO 2 filters were evaluated for the photocatalytic degradation of Rhodamine B under UV light. Among the tested structures, the gyroid geometry exhibited the highest performance (completely degrading Rhodamine B in 200 minutes) due to its higher surface area.

Ceramics InternationalVol. 52(1)
University of Rome Tor Vergata (IT), Policlinico Tor Vergata (IT)
Openalex Percentile: Top 73%
TiO2 Photocatalysis and Solar Cells
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Influence of infill geometry on the degradation performance of 3D printed TiO2 photocatalytic filters — Claudia Mazzuca, F. Nanni, et al. · Ceramics International (2025) | TGRS Research Map | TGRS