Elasticity of davemaoite as a primary contributor to lower-mantle heterogeneities
Geophysical detection of subducted mid-ocean ridge basalt (MORB) in the lower mantle is hindered by uncertainties in the elasticity of Fe,Al,Mg,Ti-bearing davemaoite, a key MORB component. Using Brillouin spectroscopy and x-ray diffraction, we determined the elasticity of a Ca<sub>0.906(1)</sub>Fe<sup>2+</sup><sub>0.027(1)</sub>Fe<sup>3+</sup><sub>0.042(1)</sub>Mg<sub>0.033(1)</sub>Al<sub>0.072(1)</sub>Ti<sub>0.020(1)</sub>Si<sub>0.912(1)</sub>O<sub>3</sub> davemaoite up to 113 gigapascals and 2294 K. We found that it exhibited a shear wave velocity 10 to 20% slower than end-member davemaoite, making it the slowest phase among major lower-mantle minerals. Our models show that MORB, containing 20 to 25 volume percent davemaoite, potentially contributes to large low-shear-velocity provinces (LLSVPs), whereas a cumulate layer enriched in davemaoite crystallized from basal magma ocean may comprise ultralow-velocity zones (ULVZs). Davemaoite's ability to host incompatible and heat-producing elements possibly links LLSVPs and ULVZs to mantle plume initiation and geochemical signatures of ocean island basalts.
Authors
- Phuong Q. H. Nguyen (ORCID: https://orcid.org/0000-0003-0947-2920)
- Wen‐Yi Zhou (ORCID: https://orcid.org/0000-0002-5712-1992)
- Sibo Chen (ORCID: https://orcid.org/0000-0002-0300-108X)
- Jin S. Zhang (ORCID: https://orcid.org/0000-0002-1936-7780)
- Taehyun Kim (ORCID: https://orcid.org/0000-0003-1950-6258)
- Dongzhou Zhang (ORCID: https://orcid.org/0000-0002-6679-892X)
- Wen‐Hao Su (ORCID: https://orcid.org/0000-0003-1745-4722)
- Katherine Armstrong (ORCID: https://orcid.org/0000-0001-6970-4573)
- Ming Hao (ORCID: https://orcid.org/0000-0003-1380-3569)
- Sang‐Heon Shim (ORCID: https://orcid.org/0000-0001-5203-6038)
Institutions
- Argonne National Laboratory (US)
- Lawrence Berkeley National Laboratory (US)
- University of California, Santa Cruz (US)
- ETH Zurich (CH)
- University of Chicago (US)
- University of Bayreuth (DE)
- Arizona State University (US)
- Texas A&M University (US)
Publication Details
- Journal
- Science
- Published
- 2025-11-27
- DOI
- https://doi.org/10.1126/science.adx8356
- Citations
- 1
- Primary Topic
- High-pressure geophysics and materials
- Type
- article
- Field-Weighted Citation Impact
- 1.87