Elasticity of davemaoite as a primary contributor to lower-mantle heterogeneities

Geophysical detection of subducted mid-ocean ridge basalt (MORB) in the lower mantle is hindered by uncertainties in the elasticity of Fe,Al,Mg,Ti-bearing davemaoite, a key MORB component. Using Brillouin spectroscopy and x-ray diffraction, we determined the elasticity of a Ca<sub>0.906(1)</sub>Fe<sup>2+</sup><sub>0.027(1)</sub>Fe<sup>3+</sup><sub>0.042(1)</sub>Mg<sub>0.033(1)</sub>Al<sub>0.072(1)</sub>Ti<sub>0.020(1)</sub>Si<sub>0.912(1)</sub>O<sub>3</sub> davemaoite up to 113 gigapascals and 2294 K. We found that it exhibited a shear wave velocity 10 to 20% slower than end-member davemaoite, making it the slowest phase among major lower-mantle minerals. Our models show that MORB, containing 20 to 25 volume percent davemaoite, potentially contributes to large low-shear-velocity provinces (LLSVPs), whereas a cumulate layer enriched in davemaoite crystallized from basal magma ocean may comprise ultralow-velocity zones (ULVZs). Davemaoite's ability to host incompatible and heat-producing elements possibly links LLSVPs and ULVZs to mantle plume initiation and geochemical signatures of ocean island basalts.

Authors

Institutions

Publication Details

Journal
Science
Published
2025-11-27
DOI
https://doi.org/10.1126/science.adx8356
Citations
1
Primary Topic
High-pressure geophysics and materials
Type
article
Field-Weighted Citation Impact
1.87
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Elasticity of davemaoite as a primary contributor to lower-mantle heterogeneities

Phuong Q. H. Nguyen, Wen‐Yi Zhou, Sibo Chen, Jin S. Zhang et al.
1 citations
Science
High-pressure geophysics and materials
1.87
article

Elasticity of davemaoite as a primary contributor to lower-mantle heterogeneities

Phuong Q. H. Nguyen, Wen‐Yi Zhou, Sibo Chen, Jin S. Zhang, Taehyun Kim, Dongzhou Zhang, Wen‐Hao Su, Katherine Armstrong, Ming Hao, Sang‐Heon Shim
article en
1 citations

Abstract

Geophysical detection of subducted mid-ocean ridge basalt (MORB) in the lower mantle is hindered by uncertainties in the elasticity of Fe,Al,Mg,Ti-bearing davemaoite, a key MORB component. Using Brillouin spectroscopy and x-ray diffraction, we determined the elasticity of a Ca<sub>0.906(1)</sub>Fe<sup>2+</sup><sub>0.027(1)</sub>Fe<sup>3+</sup><sub>0.042(1)</sub>Mg<sub>0.033(1)</sub>Al<sub>0.072(1)</sub>Ti<sub>0.020(1)</sub>Si<sub>0.912(1)</sub>O<sub>3</sub> davemaoite up to 113 gigapascals and 2294 K. We found that it exhibited a shear wave velocity 10 to 20% slower than end-member davemaoite, making it the slowest phase among major lower-mantle minerals. Our models show that MORB, containing 20 to 25 volume percent davemaoite, potentially contributes to large low-shear-velocity provinces (LLSVPs), whereas a cumulate layer enriched in davemaoite crystallized from basal magma ocean may comprise ultralow-velocity zones (ULVZs). Davemaoite's ability to host incompatible and heat-producing elements possibly links LLSVPs and ULVZs to mantle plume initiation and geochemical signatures of ocean island basalts.

ScienceVol. 390(6776)
Argonne National Laboratory (US), Lawrence Berkeley National Laboratory (US), University of California, Santa Cruz (US), ETH Zurich (CH), University of Chicago (US), University of Bayreuth (DE), Arizona State University (US), Texas A&M University (US)
Openalex Percentile: Top 12%
High-pressure geophysics and materials
1.87
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.