Exploring the Potential of R744 as a Sustainable Refrigerant for Marine Applications: A Comparative Performance Analysis with Current Refrigeration Framework

In the naval sector, hydrofluorocarbons (HFCs) are the primary refrigerants in use. To face global environmental challenges, international treaties have established stringent regulations aimed at transitioning towards more sustainable alternatives. Natural refrigerants are proposed as valid solutions, with a particular focus on carbon dioxide (R744) due to its very low direct environmental impact and high safety. This paper evaluates the potential of using R744 as a refrigerant for refrigeration systems onboard cruise ships; based on the R744 innovative solutions currently proposed in the literature for cruise ship applications, the aim is to assess whether the transition to R744 would provide advantages in terms of energy performance and total environmental impact compared with conventional systems employing HFCs. The analysis includes a description of the conventional provision and air conditioning systems mounted onboard and innovative technologies utilizing R744 as a refrigerant, proposed in the literature. These systems are numerically analyzed and compared. The numerical results show that the exclusive use of R744 in onboard systems would significantly reduce the direct environmental impact compared with the current HFCs-based configurations. However, when considering the total impact, further technological advancements in R744 systems are required to achieve a reduction in indirect emissions as well. While progressing toward full R744 adoption, some promising pathways are proposed to enhance current system efficiency.