On the nature of the red shift in absorption spectra of β-dicarbonyl chelates
This work offers an interpretation of the red shift in the spectra of mononuclear dicarbonyl chelates. The spectral effect relates to O–O′ distance and depends on the coupling between 2pσ z orbitals of oxygen atoms and d-orbitals of the metal ion.
Authors
- Maxim A. Lutoshkin (ORCID: https://orcid.org/0000-0002-3212-4206)
Institutions
- Institute of Chemistry and Chemical Technology (RU)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-11-15
- DOI
- https://doi.org/10.1039/d5nj03964a
- Primary Topic
- Photochemistry and Electron Transfer Studies
- Type
- article
- Field-Weighted Citation Impact
- 0.00