Acidity/hydridicity evaluation of Sb–H bonds and formation of a new group 15 metal cluster topology
Ambiphilic Sb–H bonds have been explored with both proton acceptors and hydride abstractors. Reactions with LiHMDS have also afforded a never-before-seen anionic triantimony chain as a lithium salt, and octameric antimony cluster.
Authors
- Tanner George (ORCID: https://orcid.org/0000-0001-7284-9132)
- Saurabh S. Chitnis (ORCID: https://orcid.org/0000-0001-9180-7907)
- Mitchell A. Z. MacEachern
Institutions
- Dalhousie University (CA)
- University of Victoria (CA)
- Saint Mary's University (CA)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-11-27
- DOI
- https://doi.org/10.1039/d5qi02115d
- Primary Topic
- Synthesis and characterization of novel inorganic/organometallic compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00