Cesium Effect: Metal- and Ligand-Free N-(Hetero)Arylation of Sulfoximines

Abstract A metal- and ligand-free Cs2CO3-promoted protocol for the N-(hetero)aryl functionalization of sulfoximines. The synthetic methodology exhibits a broad substrate scope, and the mild reaction conditions enable the functionalization of chiral sulfoximines with complete retention of configuration.

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Publication Details

Journal
Synthesis
Published
2025-11-26
DOI
https://doi.org/10.1055/a-2740-7139
Primary Topic
Synthesis and Catalytic Reactions
Type
article
Field-Weighted Citation Impact
0.00
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article

Cesium Effect: Metal- and Ligand-Free N-(Hetero)Arylation of Sulfoximines

Vinay Bharadwaj Tatipamula, Anant R. Kapdi, Suyog Adhav
Synthesis
Synthesis and Catalytic Reactions
article

Cesium Effect: Metal- and Ligand-Free N-(Hetero)Arylation of Sulfoximines

Vinay Bharadwaj Tatipamula, Anant R. Kapdi, Suyog Adhav
article en

Abstract

Abstract A metal- and ligand-free Cs2CO3-promoted protocol for the N-(hetero)aryl functionalization of sulfoximines. The synthetic methodology exhibits a broad substrate scope, and the mild reaction conditions enable the functionalization of chiral sulfoximines with complete retention of configuration.

SynthesisVol. 58(03)
Institute of Chemical Technology (IN), Tata Chemicals (India) (IN)
Openalex Percentile: Top 72%
Synthesis and Catalytic Reactions
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