Proof-of-concept and model validation of chemical looping reforming of glycerol at relevant conditions

• Oxidation, Reduction and Reforming kinetics determined using Thermogravimetric analysis. • 1D axially dispersed pseudo-homogeneous model of chemical looping C 3 H 8 O 3 developed. • Ni-based chemical looping reforming of C 3 H 8 O 3 was tested up to 900 °C and 5 bar a using 500 g of oxygen carrier. • Model and kinetics validated with outlet gas and axial temperature during steady cycling behaviour. Chemical looping reforming (CLR) of glycerol was experimentally and numerically investigated to demonstrate syngas production with integrated in-situ oxygen transfer and heat recovery. A shrinking core model was developed using a Ni-based catalyst, and a 1-dimensional pseudo-homogeneous, axially dispersed plug flow model was validated against laboratory-scale experiments. The packed-bed reactor, containing 500 g of oxygen carrier, showed stable performance over 500 hours with conditions being between 400–900 °C and 1–5 bar a . During the air oxidation, a temperature rise of 340 °C of generated from the initial 500 °C. The model achieved excellent agreement with experimental results, using a heat loss coefficient of 46 W·m −2 ·K -1 accurtatly predicting the exothermic oxidation, thermally neutral reduction and endothermic reduction stage. The combined steam and dry reforming of glycerol generated that syngas ratio of 2.3–3.6, where carbon balances closed within ±7 % with no carbon deposition, whilst maintaining CH 4 formation below 1 vol% and a carbon conversion of >95 %. The results confirm that CLR of glycerol can deliver stable redox cycles, favourable syngas composition for downstream Fischer-Tropsch or methanol synthesis and enhances process efficiency for biofuel production and CO 2 mitigation.