Ruthenium Bis-Sulfonate Complexes: Synthesis and Application in Asymmetric Hydrogenation
A series of Ru-(L)-(X)<sub>2</sub> complexes (L = bidentate ligand; X = OMs, OTs, OTf) was synthesized and characterized. Ru-(BINAP)-(OMs)<sub>2</sub> showed improved catalytic performance over the established Ru-(BINAP)-(OAc)<sub>2</sub> catalyst, highlighting the impact of anion variation on catalytic asymmetric hydrogenations.
Authors
- Fedor M. Miloserdov (ORCID: https://orcid.org/0000-0001-6420-211X)
- Yifei Zhou (ORCID: https://orcid.org/0000-0002-2792-3599)
- Olga O. Sokolova (ORCID: https://orcid.org/0000-0002-1740-7662)
- P. Vink (ORCID: https://orcid.org/0009-0006-8181-8120)
- İbrahim Kılınç
Institutions
- Radboud University Nijmegen (NL)
- Wageningen University & Research (NL)
Publication Details
- Journal
- Organometallics
- Published
- 2025-11-10
- DOI
- https://doi.org/10.1021/acs.organomet.5c00388
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00