Regiodivergent gold( <scp>i</scp> )-catalysed rearrangements in indole synthesis
The gold( i )-catalysed [3,4]-sigmatropic rearrangement of 2-alkynyl anilines having electron-withdrawing benzylic groups, yield o -tolylindoles in a non-common methylene to methyl transformation.
Authors
- César R. Solorio‐Alvarado (ORCID: https://orcid.org/0000-0001-6082-988X)
- Rafael Ortíz‐Alvarado (ORCID: https://orcid.org/0000-0001-8169-3838)
- Jesús Adrián López (ORCID: https://orcid.org/0000-0001-8012-7041)
- Gabriel Merino (ORCID: https://orcid.org/0000-0003-1961-8321)
- Luis Chacón-Garcı́a (ORCID: https://orcid.org/0000-0001-8877-4817)
- Fernando Murillo (ORCID: https://orcid.org/0000-0002-1688-6008)
- Edson D. Hernández‐Velázquez (ORCID: https://orcid.org/0000-0002-5442-7339)
- Ana K. García-Dueñas
- Jaime G. Ibarra‐Gutiérrez (ORCID: https://orcid.org/0009-0009-6761-0712)
Institutions
- Universidad de Guanajuato (MX)
- Universidad Michoacana de San Nicolás de Hidalgo (MX)
- Universidad Marista de Mérida (MX)
- Universidad Autónoma de Zacatecas "Francisco García Salinas" (MX)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-11-12
- DOI
- https://doi.org/10.1039/d5qo01326g
- Primary Topic
- Catalytic Alkyne Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00