Azo-Functional Indium-Based Metal–Organic Framework as a High-Performance Organic Iodides Adsorbent

To handle waste gas from nuclear fuel reprocessing, the precise design and preparation of materials exhibiting high-efficiency organic iodide capture performance are still facing huge challenges owing to the severe lack of efficient affinity sites. Herein, we selected an indium-based metal-organic framework, <b>SHF-61</b>, as a precursor and successfully obtained functionalized material, <b>Post-SHF-61</b>, with an azo bond by the diazo coupling reaction between aniline and the amino group of <b>SHF-61</b>. As a result, the conjugation and electron density of the organic component in <b>SHF-61</b> were significantly enhanced. Static organic iodide adsorption experiments indicated that the CH₃I and C₂H₅I adsorption capacities of 1545 and 848 mg/g for <b>Post-SHF-61</b> were obviously higher than that of 591 and 271 mg/g for <b>SHF-61</b> at 75 °C under the same condition. Additionally, the CH₃I and C₂H₅I adsorption mechanisms of <b>SHF-61</b> and <b>Post-SHF-61</b> and the possible presence of iodide species in these aforementioned materials were further determined in detail. This study provides some beneficial guides for the development of metal-organic framework-based materials with high organic iodide adsorption capacity.