Ni‐Catalyzed Thioetherification of Alkyl and Aryl Thiols With Aryl Bromides Under Base‐Free Condition
A method for Ni-catalyzed coupling of thiophenols and thiols with aryl bromides is described. The reactions proceed under mild, base-free conditions and accommodate the coupling of tertiary alkyl thiols, aryl thiols, and cysteine derivatives with aryl electrophiles, yielding alkyl-aryl and diaryl thioethers in moderate to high yields.
Authors
- Demin Liang
- Yunrong Chen (ORCID: https://orcid.org/0000-0001-6872-4943)
- Jiale Wang (ORCID: https://orcid.org/0000-0003-3830-1995)
- Yanhong Song (ORCID: https://orcid.org/0000-0002-4019-8213)
- Wu Da
- Yuxin Gong (ORCID: https://orcid.org/0000-0002-1915-7978)
Institutions
- University of Shanghai for Science and Technology (CN)
- China Tobacco (CN)
Publication Details
- Journal
- Chemistry - An Asian Journal
- Published
- 2025-11-23
- DOI
- https://doi.org/10.1002/asia.70443
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.00