Dislocation response to electric fields in strontium titanate: A mesoscale indentation study

Abstract Dislocations in perovskite oxides have drawn increasing research interest due to their potential for tuning functional properties of electroceramics. Open questions remain regarding the stability of dislocations under strong externally applied electric fields. In this study, we investigate the dielectric breakdown strength of nominally undoped SrTiO 3 crystals after the introduction of high‐density dislocations. The dislocation‐rich samples are prepared using the Brinell scratching method, and they consistently exhibit lower dielectric breakdown strength as well as a larger scatter in the breakdown probability. We also study the impact of an electric field on the introduction and movement of dislocations in SrTiO 3 crystals using Brinell indentation coupled with an electric field of 2 kV/mm. No visible changes in the dislocation plastic zone size, depth, and dislocation distribution are observed under this electric field. Based on the charge state of the dislocations in SrTiO 3 as well as the electrical and thermal conductivity modified by dislocations, we discuss the forces induced by the electric field to act on the dislocations to underline the possible mechanisms for such dislocation behavior.