Advanced machine-learning frameworks for predicting malachite green adsorption onto superparamagnetic-activated carbon derived from Spathodea campanulata flowers

• Developed and compared MLR, ANN, ANFIS, and SVM for MG adsorption prediction. • ANFIS achieved the highest predictive accuracy (R 2 = 0.9683) with lowest errors. • ANN and SVM showed strong complementary predictive performance. • Contact time emerged as the most influential process variable. This investigation introduces a comprehensive machine-learning (ML) scheme for accurately predicting the uptake of the cationic dye Malachite Green (MG) onto superparamagnetic activated carbon derived from Spathodea campanulata flowers. Batch adsorption experiments data covering a wide range of solution pH, sorbent dosage, initial dye concentration, contact time, and temperature were used to compare four predictive models: multiple linear regression (MLR), artificial neural network (ANN), adaptive neuro-fuzzy inference system (ANFIS), and support vector machine (SVM). Pearson correlation analysis revealed contact time as the dominant positive factor influencing adsorption capacity (Q e ). Among MLR variants, the interaction-linear model achieved the best fit (R 2 = 0.8901). SVM with a medium Gaussian kernel improved accuracy substantially (R 2 = 0.9577). ANN delivered similarly strong predictive power (overall R 2 =0.9672) by learning complex multidimensional patterns. ANFIS emerged as the most robust and generalizable model, achieving R 2 = 0.9683 with the lowest mean squared error (0.0098), root mean squared error (0.0992), and mean absolute error (0.0311). Sensitivity analysis of the optimized ANFIS confirmed the primacy of contact time (56.8 %), followed by initial concentration (33.2 %), dosage (3.6 %), temperature (3.3 %), and pH (3.1 %). This integrated experimental–computational approach offers a scalable, data-driven strategy for designing magnetically recoverable adsorbents and optimizing dye remediation in complex wastewater matrices.

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Journal
South African Journal of Chemical Engineering
Published
2025-11-21
DOI
https://doi.org/10.1016/j.sajce.2025.11.017
Primary Topic
Adsorption and biosorption for pollutant removal
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article
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article

Advanced machine-learning frameworks for predicting malachite green adsorption onto superparamagnetic-activated carbon derived from Spathodea campanulata flowers

Ramesh Vinayagam, Raja Selvaraj, Sujesh Sudarsan
South African Journal of Chemical Engineering
Adsorption and biosorption for pollutant removal
article

Advanced machine-learning frameworks for predicting malachite green adsorption onto superparamagnetic-activated carbon derived from Spathodea campanulata flowers

Ramesh Vinayagam, Raja Selvaraj, Sujesh Sudarsan
article en

Abstract

• Developed and compared MLR, ANN, ANFIS, and SVM for MG adsorption prediction. • ANFIS achieved the highest predictive accuracy (R 2 = 0.9683) with lowest errors. • ANN and SVM showed strong complementary predictive performance. • Contact time emerged as the most influential process variable. This investigation introduces a comprehensive machine-learning (ML) scheme for accurately predicting the uptake of the cationic dye Malachite Green (MG) onto superparamagnetic activated carbon derived from Spathodea campanulata flowers. Batch adsorption experiments data covering a wide range of solution pH, sorbent dosage, initial dye concentration, contact time, and temperature were used to compare four predictive models: multiple linear regression (MLR), artificial neural network (ANN), adaptive neuro-fuzzy inference system (ANFIS), and support vector machine (SVM). Pearson correlation analysis revealed contact time as the dominant positive factor influencing adsorption capacity (Q e ). Among MLR variants, the interaction-linear model achieved the best fit (R 2 = 0.8901). SVM with a medium Gaussian kernel improved accuracy substantially (R 2 = 0.9577). ANN delivered similarly strong predictive power (overall R 2 =0.9672) by learning complex multidimensional patterns. ANFIS emerged as the most robust and generalizable model, achieving R 2 = 0.9683 with the lowest mean squared error (0.0098), root mean squared error (0.0992), and mean absolute error (0.0311). Sensitivity analysis of the optimized ANFIS confirmed the primacy of contact time (56.8 %), followed by initial concentration (33.2 %), dosage (3.6 %), temperature (3.3 %), and pH (3.1 %). This integrated experimental–computational approach offers a scalable, data-driven strategy for designing magnetically recoverable adsorbents and optimizing dye remediation in complex wastewater matrices.

South African Journal of Chemical EngineeringVol. 55
Manipal Academy of Higher Education (IN)
Openalex Percentile: Top 67%
Adsorption and biosorption for pollutant removal
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Advanced machine-learning frameworks for predicting malachite green adsorption onto superparamagnetic-activated carbon derived from Spathodea campanulata flowers — Ramesh Vinayagam, Raja Selvaraj, et al. · South African Journal of Chemical Engineering (2025) | TGRS Research Map | TGRS