Study on Sulfide Stress Corrosion Cracking Susceptibility of 20# Steel Weld Joints in H2S-Rich Environments

This study aims to clarify the influence of H<sub>2</sub>S concentration and temperature on the sulfide stress corrosion cracking (SSCC) susceptibility of 20# steel weld joints. 20# steel is a commonly selected pipe material for ground gas pipelines, and there is a risk of welds cracking after years of service. The selection of a corrosive environment is based on the working conditions of high-sulfur oil fields on site. Slow strain rate tensile (SSRT) tests were conducted under simulated high-sulfur gathering and transportation conditions across varying temperatures and H<sub>2</sub>S concentrations. The mechanical properties, SSCC susceptibility, fracture morphology, and elemental composition of fracture surfaces were systematically analyzed. As H<sub>2</sub>S concentration increased (5%, 7.5%, 10%) and temperature decreased (30-60 °C), the elongation after fracture and the reduction in area of 20# steel decreased, while the yield strength and SSCC susceptibility increased. The H<sub>2</sub>S concentration range of 0-5% represented a critical sensitivity interval for the material, where elongation after fracture decreased by up to 74%. Within the 5-10% H<sub>2</sub>S range, elongation decreased by only 2.11%, indicating a slowing trend of fracture toughness deterioration, though SSCC susceptibility still increased by 12%. Increasing the temperature from 30 °C to 60 °C reduced SSCC susceptibility by approximately 30%, confirming higher susceptibility at lower temperatures. Temperature exerts a lesser influence on material performance than H<sub>2</sub>S concentration. Also, 20# steel remains within the SSCC brittle fracture sensitivity zone in sulfur-containing environments, necessitating strict quality control to avoid defects and stress concentrations. In high-sulfur environments (H<sub>2</sub>S > 5%), further increases in H<sub>2</sub>S concentration have a diminished effect on cracking susceptibility.

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Publication Details

Journal
Molecules
Published
2025-11-21
DOI
https://doi.org/10.3390/molecules30234499
Citations
1
Primary Topic
Fatigue and fracture mechanics
Type
article
Field-Weighted Citation Impact
0.86
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article

Study on Sulfide Stress Corrosion Cracking Susceptibility of 20# Steel Weld Joints in H2S-Rich Environments

Ting Mao, Yanqi Ran, Zhiming Yu, Xinze Li
1 citations
Molecules
Fatigue and fracture mechanics
0.86
article

Study on Sulfide Stress Corrosion Cracking Susceptibility of 20# Steel Weld Joints in H2S-Rich Environments

Ting Mao, Yanqi Ran, Zhiming Yu, Xinze Li
article en
1 citations

Abstract

This study aims to clarify the influence of H<sub>2</sub>S concentration and temperature on the sulfide stress corrosion cracking (SSCC) susceptibility of 20# steel weld joints. 20# steel is a commonly selected pipe material for ground gas pipelines, and there is a risk of welds cracking after years of service. The selection of a corrosive environment is based on the working conditions of high-sulfur oil fields on site. Slow strain rate tensile (SSRT) tests were conducted under simulated high-sulfur gathering and transportation conditions across varying temperatures and H<sub>2</sub>S concentrations. The mechanical properties, SSCC susceptibility, fracture morphology, and elemental composition of fracture surfaces were systematically analyzed. As H<sub>2</sub>S concentration increased (5%, 7.5%, 10%) and temperature decreased (30-60 °C), the elongation after fracture and the reduction in area of 20# steel decreased, while the yield strength and SSCC susceptibility increased. The H<sub>2</sub>S concentration range of 0-5% represented a critical sensitivity interval for the material, where elongation after fracture decreased by up to 74%. Within the 5-10% H<sub>2</sub>S range, elongation decreased by only 2.11%, indicating a slowing trend of fracture toughness deterioration, though SSCC susceptibility still increased by 12%. Increasing the temperature from 30 °C to 60 °C reduced SSCC susceptibility by approximately 30%, confirming higher susceptibility at lower temperatures. Temperature exerts a lesser influence on material performance than H<sub>2</sub>S concentration. Also, 20# steel remains within the SSCC brittle fracture sensitivity zone in sulfur-containing environments, necessitating strict quality control to avoid defects and stress concentrations. In high-sulfur environments (H<sub>2</sub>S > 5%), further increases in H<sub>2</sub>S concentration have a diminished effect on cracking susceptibility.

MoleculesVol. 30(23)
China University of Petroleum, Beijing (CN), University of Kara (TG), Karamay Central Hospital (CN), Gas Technology Institute (US)
Openalex Percentile: Top 22%
Fatigue and fracture mechanics
0.86
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