One-pot synthesis of novel triazine/piperazine-based macrocycles and investigation of their porous properties
Four macrocycles with the penta-triazine and penta-piperazine scaffold were efficiently synthesized <i>via</i> self-cyclization in 15-23% yields; the synthesized macrocycles were assumed to have crown-shaped conformations by NMR spectroscopy and computational simulations and contain void spaces in the bulky state by CO<sub>2</sub> isotherms.
Authors
- H.N. Cheng
- Hou‐Jen Lai (ORCID: https://orcid.org/0009-0002-2492-5764)
- Hsiu‐Fu Hsu (ORCID: https://orcid.org/0000-0003-0309-2601)
- Long‐Li Lai (ORCID: https://orcid.org/0000-0002-2152-0430)
- Yao-Chih Lu
Institutions
- Tamkang University (TW)
- National Chi Nan University (TW)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-11-21
- DOI
- https://doi.org/10.1039/d5cc05684e
- Primary Topic
- Synthesis and Characterization of Heterocyclic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00