Ensemble cure kinetics network (ECK-Net): A method to derive cure kinetics of thermosetting resin

• Derive cure kinetics of thermosetting resins using an ensemble neural network. • Introduce a validation framework that evaluates full cure scenarios with multiple metrics and mitigates overfitting. • Demonstrate generalizability of the proposed model across multiple resin systems and cure cycle with experimental verification. This paper introduces an Ensemble Cure Kinetics Network (ECK-Net), a neural network (NN)–based framework for modeling the cure kinetics of thermosetting resins within a phenomenological context. ECK-Net replaces traditional analytic models, which require extensive chemical insight and multiple isothermal/non-isothermal experiments, with a data-driven surrogate that maps nonlinear relationships between temperature, degree of cure, and reaction rate from differential scanning calorimetry data. The proposed approach predicts input-dependent kinetic coefficients of a generalized nth-order reaction equation rather than reaction rates directly, enabling a single unified model to represent various epoxy systems without relying on iso -conversional analysis or predefined functional forms. To ensure robustness, multiple independently trained networks under different random initializations are blended through an ensemble strategy, effectively mitigating the stochastic variability inherent to neural networks. The framework is validated using experimental datasets from multiple resin systems, including aerospace-grade materials (Toray 3900-2, Cycom 5320-1, and Hexcel 8552) and a windmill-grade resin (RIMR 035c). The model accurately reproduces the temporal evolution of the degree of cure under manufacturers’ recommended cure cycles across all tested resins systems, yielding Pearson’s correlation coefficients of 0.992, 0.994, 0.993, 0.997, respectively. To demonstrate process-level applicability, the trained network was implemented within the Abaqus environment to simulate out-of-autoclave (OOA) curing process of the CFRP panel composed of Toray T830H-6K/3900-2D prepreg. The simulation results showed excellent agreement with experimental temperature response (maximum peak temperature, simulation: 189.6 °C, experiment: 188.5 °C) and the final degree of cure (simulation: 0.948, experiment: 0.960 ± 0.013), confirming ECK-Net’s capability as a reliable alternative to conventional cure kinetics modeling methods.

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Publication Details

Journal
Composites Part A Applied Science and Manufacturing
Published
2025-11-21
DOI
https://doi.org/10.1016/j.compositesa.2025.109453
Primary Topic
Epoxy Resin Curing Processes
Type
article
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article

Ensemble cure kinetics network (ECK-Net): A method to derive cure kinetics of thermosetting resin

Geun Young Kim, Jonathan S. Colton, Shreyes N. Melkote
Composites Part A Applied Science and Manufacturing
Epoxy Resin Curing Processes
article

Ensemble cure kinetics network (ECK-Net): A method to derive cure kinetics of thermosetting resin

Geun Young Kim, Jonathan S. Colton, Shreyes N. Melkote
article en

Abstract

• Derive cure kinetics of thermosetting resins using an ensemble neural network. • Introduce a validation framework that evaluates full cure scenarios with multiple metrics and mitigates overfitting. • Demonstrate generalizability of the proposed model across multiple resin systems and cure cycle with experimental verification. This paper introduces an Ensemble Cure Kinetics Network (ECK-Net), a neural network (NN)–based framework for modeling the cure kinetics of thermosetting resins within a phenomenological context. ECK-Net replaces traditional analytic models, which require extensive chemical insight and multiple isothermal/non-isothermal experiments, with a data-driven surrogate that maps nonlinear relationships between temperature, degree of cure, and reaction rate from differential scanning calorimetry data. The proposed approach predicts input-dependent kinetic coefficients of a generalized nth-order reaction equation rather than reaction rates directly, enabling a single unified model to represent various epoxy systems without relying on iso -conversional analysis or predefined functional forms. To ensure robustness, multiple independently trained networks under different random initializations are blended through an ensemble strategy, effectively mitigating the stochastic variability inherent to neural networks. The framework is validated using experimental datasets from multiple resin systems, including aerospace-grade materials (Toray 3900-2, Cycom 5320-1, and Hexcel 8552) and a windmill-grade resin (RIMR 035c). The model accurately reproduces the temporal evolution of the degree of cure under manufacturers’ recommended cure cycles across all tested resins systems, yielding Pearson’s correlation coefficients of 0.992, 0.994, 0.993, 0.997, respectively. To demonstrate process-level applicability, the trained network was implemented within the Abaqus environment to simulate out-of-autoclave (OOA) curing process of the CFRP panel composed of Toray T830H-6K/3900-2D prepreg. The simulation results showed excellent agreement with experimental temperature response (maximum peak temperature, simulation: 189.6 °C, experiment: 188.5 °C) and the final degree of cure (simulation: 0.948, experiment: 0.960 ± 0.013), confirming ECK-Net’s capability as a reliable alternative to conventional cure kinetics modeling methods.

Composites Part A Applied Science and ManufacturingVol. 201
Georgia Institute of Technology (US)
Openalex Percentile: Top 63%
Epoxy Resin Curing Processes
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