Study of Properties of Tetramethylammonium Perchlorate and Some Explosive Compositions Based on It

This paper presents thermodynamic calculations of characteristics of explosive mixtures based on tetramethylammonium perchlorate. Their sensitivity, explosion heat, and volume are determined. The composition of gaseous explosion products is analyzed. This paper also demonstrates the possibility of creating promising explosive mixtures with detonability and mechanical sensitivity in the TNT–RDX range, with an explosion heat of higher than 6 MJ/kg and a hydrogen content of gaseous explosion products of more than 50 vol %.

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Publication Details

Journal
Combustion Explosion and Shock Waves
Published
2025-04-01
DOI
https://doi.org/10.1134/s0010508225700121
Primary Topic
Energetic Materials and Combustion
Type
article
Field-Weighted Citation Impact
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article

Study of Properties of Tetramethylammonium Perchlorate and Some Explosive Compositions Based on It

A. S. Gubin, Ekaterina S. Manakhova, M. N. Tereshchenko, P. S. Chernavkin et al.
Combustion Explosion and Shock Waves
Energetic Materials and Combustion
article

Study of Properties of Tetramethylammonium Perchlorate and Some Explosive Compositions Based on It

A. S. Gubin, Ekaterina S. Manakhova, M. N. Tereshchenko, P. S. Chernavkin, V. I. Kolesov
article en

Abstract

This paper presents thermodynamic calculations of characteristics of explosive mixtures based on tetramethylammonium perchlorate. Their sensitivity, explosion heat, and volume are determined. The composition of gaseous explosion products is analyzed. This paper also demonstrates the possibility of creating promising explosive mixtures with detonability and mechanical sensitivity in the TNT–RDX range, with an explosion heat of higher than 6 MJ/kg and a hydrogen content of gaseous explosion products of more than 50 vol %.

Combustion Explosion and Shock WavesVol. 61(2)
D. Mendeleyev University of Chemical Technology of Russia (RU), State Research Institute of Mechanical Engineering (RU)
Openalex Percentile: Top 60%
Energetic Materials and Combustion
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