Sustainable solid-state polymer electrolyte based on PEO-Xanthan gum blend for enhanced lithium-metal batteries

Despite their widespread adoption, LIBs are still facing several challenges, mainly related with safety concerns of conventional electrolytes that are currently limiting their practical use. Solid-state polymer electrolytes (SPEs) represent a promising alternative to produce safer devices, as they offer higher flexibility and energy density, easy processability, non-flammability and improved mechanical strength, even if they often suffer from low ionic conductivity at room temperature. To address the latter issue, the development of novel SPEs based on a blend of polyethylene oxide (PEO) and Xanthan gum (XG), a natural polysaccharide with notable mechanical and rheological properties, is proposed. In this study, the thermal, physical, and electrochemical properties of the PEO-XG blends were investigated, aiming to assess their potential as electrolyte for all solid-state lithium metal batteries. Improved ionic conductivity, electrochemical stability window and cycling stability are achieved, confirming the effectiveness of XG incorporation. The most promising electrolyte formulation was studied using self-diffusion 7 Li pulse-field-gradient (PFG) NMR measurements and different temperatures and further evaluated in full-cell configurations employing two olivine-type cathodes (LFP and LMFP). When paired with a lithium manganese iron phosphate (LMFP) cathode and cycled over an extended voltage window of 2.5–4.5 V, the cell demonstrates high specific capacity and excellent capacity retention, maintaining stable performance for at least 750 cycles. • PEO/Xanthan Gum-based Solid Polymer Electrolytes are synthesized and characterized. • The most suitable composition is given by a blend PEO:XG 80:20, with LiTFSI salt. • Transport properties are assessed by NMR and electrochemical methods. • The electrochemical stability window lies in the 0.01 V < E < 4.8 V. • The SPE is compatible with metal Li anode and olivine-type cathodes (LFP and LFMP).