Ferromagnetic moment in the magnetoelectric antiferromagnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Co</mml:mi> <mml:mn>4</mml:mn> </mml:msub> <mml:msub> <mml:mi>Ta</mml:mi> <mml:mn>2</mml:mn> </mml:msu
Exploring ferromagnetic moments in magnetoelectric materials is of both fundamental and technological importance. It enables the control of the correlated state using an uncompensated moment. However, its material realization is challenging owing to its exclusive microscopic mechanisms. Here, we report a nearly isotropic ferromagnetic moment in the magnetoelectric antiferromagnet <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"> <a:mrow> <a:msub> <a:mi>Co</a:mi> <a:mn>4</a:mn> </a:msub> <a:msub> <a:mi>Ta</a:mi> <a:mn>2</a:mn> </a:msub> <a:msub> <a:mi mathvariant="normal">O</a:mi> <a:mn>9</a:mn> </a:msub> </a:mrow> </a:math> , by performing dc and ac magnetic susceptibility, magnetization, and neutron diffraction measurements on identical single crystals. Combined with the group theory analysis, we demonstrate a <c:math xmlns:c="http://www.w3.org/1998/Math/MathML"> <c:mrow> <c:mi>P</c:mi> <c:mn>1</c:mn> </c:mrow> </c:math> magnetic space group. This implies that physical activities can occur along any crystallographic direction, which explains the unusual magnetoelectric property of <d:math xmlns:d="http://www.w3.org/1998/Math/MathML"> <d:mrow> <d:msub> <d:mi>Co</d:mi> <d:mn>4</d:mn> </d:msub> <d:msub> <d:mi>Ta</d:mi> <d:mn>2</d:mn> </d:msub> <d:msub> <d:mi mathvariant="normal">O</d:mi> <d:mn>9</d:mn> </d:msub> </d:mrow> </d:math> . The ground state is classified as the M-type altermagnet based on the magnetic point group. Our study provides essential information to resolve the debate on the magnetic ground state and understand the magnetoelectric properties of the related compound with the prospect of observing and examining the <f:math xmlns:f="http://www.w3.org/1998/Math/MathML"> <f:mrow> <f:mi>P</f:mi> <f:mn>1</f:mn> </f:mrow> </f:math> magnetic space group or ferromagnet in ferroelectrics.
Authors
- V. Kiryukhin (ORCID: https://orcid.org/0000-0003-2754-8204)
- Rahul Goel (ORCID: https://orcid.org/0000-0003-0851-7656)
- N. Lee (ORCID: https://orcid.org/0000-0003-2592-3031)
- Dnyaneshwar R. Bhosale (ORCID: https://orcid.org/0000-0002-6486-1104)
- Sungkyun Choi (ORCID: https://orcid.org/0000-0002-8267-8581)
- Anzar Ali (ORCID: https://orcid.org/0000-0002-6390-7211)
- Young Jai Choi (ORCID: https://orcid.org/0000-0002-1711-0607)
- Dong Gun Oh (ORCID: https://orcid.org/0000-0002-4276-6384)
- Gideok Kim (ORCID: https://orcid.org/0000-0003-2667-0064)
- M. Gutmann (ORCID: https://orcid.org/0000-0001-7737-3364)
- Kwanghyo Son (ORCID: https://orcid.org/0000-0002-4751-2885)
- Kapil Kumar (ORCID: https://orcid.org/0000-0001-5079-0571)
- Sang-Wook Cheong
- Suk Jin Mun (ORCID: https://orcid.org/0009-0008-6961-2861)
Institutions
- Rutgers, The State University of New Jersey (US)
- Rutherford Appleton Laboratory (GB)
- Yonsei University (KR)
- Czech Academy of Sciences (CZ)
- Kongju National University (KR)
- Max Planck Institute for Solid State Research (DE)
- Rutgers Sexual and Reproductive Health and Rights (NL)
- Institute for Basic Science (KR)
- Max Planck Institute for Intelligent Systems (DE)
- Gongju National University of Education (KR)
- Sungkyunkwan University (KR)
Publication Details
- Journal
- Physical Review Research
- Published
- 2025-11-20
- DOI
- https://doi.org/10.1103/7gx9-wx2b
- Primary Topic
- Multiferroics and related materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00