Self-regulated bidirectional temperature gradients in radiation-modulated fabrics for diurnal thermal comfort management and energy harvesting

Harvesting low-grade heat from both human metabolism and environmental waste through thermoelectric fabrics offers a sustainable pathway for wearable power generation. However, a critical challenge exists in establishing substantial temperature differentials for continuous thermoelectric generation while maintaining physiologically comfortable skin temperatures in dynamically variable environments. Herein, we present a dynamic radiation-modulated sandwich-structured fabric capable of diurnally adaptive operation that simultaneously enables thermal comfort regulation and thermoelectric energy harvesting. Based on a parallel dual-spinneret blow-spinning technique, we engineer all-fibrous thermoelectric fabrics with asymmetric MWCNT and AgNW electrodes. The optimized sandwich fabric achieves an out-of-plane temperature gradient (Δ<em>T</em>) of 9 °C under 1 kW m^-2 daytime solar irradiation and -5 °C at night (ambient temperature of 28 °C), while maintaining skin-contact temperatures within the physiological comfort range (35.5-38.3 °C). Theoretical and experimental studies reveal that these self-regulated bidirectional temperature gradients result from asymmetric optical absorption/emission properties between the MWCNT top layer (solar absorptance <em>α</em>_solar=91%, mid-infrared emissivity <em>ε</em>_MIR=87%) and the AgNW bottom layer (<em>α</em>_solar=18%, <em>ε</em>_MIR=20%). This effect is synergistically enhanced by the hierarchical porous fibrous interlayer with confined thermal transfer. Outdoor experiments demonstrate stable diurnal operation for thermal comfort and energy harvesting, generating a peak voltage of 20 mV through modular integration of sandwich fabrics.