Glycosyl thiosulfonate-enabled <i>ortho</i> -thiolation <i>via</i> the Catellani strategy: a modular synthesis of polysubstituted aryl thioglycosides

We devised a modular approach involving glycosyl thiosulfonate-enabled ortho -C–H thioglycosylation and ipso -functionalization of aryl iodides/aryl boronic acids via palladium/norbornene cooperative catalysis and various terminations.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-11-20
DOI
https://doi.org/10.1039/d5qo01342a
Primary Topic
Carbohydrate Chemistry and Synthesis
Type
article
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article

Glycosyl thiosulfonate-enabled ortho -thiolation via the Catellani strategy: a modular synthesis of polysubstituted aryl thioglycosides

Pintu Kumar Mandal, Zanjila Azeem, Sathish Kumar Mudedla, Ruchir Kant et al.
Organic Chemistry Frontiers
Carbohydrate Chemistry and Synthesis
article

Glycosyl thiosulfonate-enabled ortho -thiolation via the Catellani strategy: a modular synthesis of polysubstituted aryl thioglycosides

Pintu Kumar Mandal, Zanjila Azeem, Sathish Kumar Mudedla, Ruchir Kant, Shalini, Neetu Malya
article en

Abstract

We devised a modular approach involving glycosyl thiosulfonate-enabled ortho -C–H thioglycosylation and ipso -functionalization of aryl iodides/aryl boronic acids via palladium/norbornene cooperative catalysis and various terminations.

Organic Chemistry FrontiersVol. 13(3)
Central Drug Research Institute (IN), Academy of Scientific and Innovative Research (IN)
Openalex Percentile: Top 73%
Carbohydrate Chemistry and Synthesis
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