Critical exponents and magnetocaloric effect of Ba1.95Ag0.05FeMoO6 double perovskite oxide

This research explores the magnetocaloric effect in the Ba 1.95 Ag 0.05 FeMoO 6 double perovskite sample, which was synthesized via the sol-gel method. The critical exponents and the magnetocaloric effect of the sample were analyzed through both experimental and theoretical methods. These were determined using an iterative approach based on the Kouvel-Fisher analysis, modified Arrott plots, and the Widom scaling law. The transition from paramagnetic to ferromagnetic phases takes place at approximately 320 K. When a magnetic field of 3 T is applied, the maximum magnetic entropy change (-ΔS M ) close to the Curie temperature (T C ) is about 0.690 J kg -1 K -1 , and the corresponding relative cooling power (RCP) at 3 T is approximately 48 J kg -1 . The magnetic entropy change was calculated using Landau theory and Maxwell's relation, demonstrating remarkable consistency.

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Publication Details

Journal
Materials Today Communications
Published
2025-11-09
DOI
https://doi.org/10.1016/j.mtcomm.2025.114289
Primary Topic
Magnetic and transport properties of perovskites and related materials
Type
article
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article

Critical exponents and magnetocaloric effect of Ba1.95Ag0.05FeMoO6 double perovskite oxide

Z. Ghorbani, T. Raoufi, M.H. Ehsani, Mohamed Hsini et al.
Materials Today Communications
Magnetic and transport properties of perovskites and related materials
article

Critical exponents and magnetocaloric effect of Ba1.95Ag0.05FeMoO6 double perovskite oxide

Z. Ghorbani, T. Raoufi, M.H. Ehsani, Mohamed Hsini, Yingde Zhang, Hong‐Guang Piao
article en

Abstract

This research explores the magnetocaloric effect in the Ba 1.95 Ag 0.05 FeMoO 6 double perovskite sample, which was synthesized via the sol-gel method. The critical exponents and the magnetocaloric effect of the sample were analyzed through both experimental and theoretical methods. These were determined using an iterative approach based on the Kouvel-Fisher analysis, modified Arrott plots, and the Widom scaling law. The transition from paramagnetic to ferromagnetic phases takes place at approximately 320 K. When a magnetic field of 3 T is applied, the maximum magnetic entropy change (-ΔS M ) close to the Curie temperature (T C ) is about 0.690 J kg -1 K -1 , and the corresponding relative cooling power (RCP) at 3 T is approximately 48 J kg -1 . The magnetic entropy change was calculated using Landau theory and Maxwell's relation, demonstrating remarkable consistency.

Materials Today CommunicationsVol. 50
Yanbian University of Science and Technology (CN), University of Monastir (TN), Yanbian University (CN), Baotou Research Institute of Rare Earths (CN), Semnan University (IR)
Openalex Percentile: Top 75%
Magnetic and transport properties of perovskites and related materials
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