Blast Nucleation Suppressed Growth of Large-Sized High-Quality CsPbBr3 Single Crystals for Photodetector Applications

During the growth of lead halide perovskite single crystals (SCs) with the conventional inverse temperature crystallization (ITC) method, the blast nucleation of the precursor under supersaturation conditions is always unavoidable. In the current study, three kinds of additives namely methanol (MOE), ethyl alcohol (EtOH), and polyethylene glycol (PEG) are introduced to regulate the growth of CsPbBr₃ SCs. Benefiting from the strong anchoring hydroxy groups (-OH) with the Pb²⁺ species, large-sized CsPbBr₃ crystals with reduced defect densities were prepared (PEG-regulated). In addition, the viscosity of the precursor solution increases after adding PEG additive, which provides a more stabilized environment for crystal growth. Finally, the photodetectors prepared from our PEG-tuned CsPbBr₃ SCs show a responsivity of 2.25 A/W and a detectivity of 6.06 × 10¹¹ Jones, demonstrating the potential of CsPbBr₃ SCs for photo-detecting applications.