Engineering hierarchical porous carbon-supported Fe-doped cobalt phosphides from MOF templates for alkaline water oxidation

A MOF-on-MOF strategy is utilized to synthesize Fe-doped cobalt phosphide nanoparticles within a porous N-doped carbon matrix (S-CoFeP). Detailed characterization confirms the successful formation of Co<sub>2</sub>P as the primary phase, with Fe incorporated as a beneficial dopant. S-CoFeP exhibits exceptional OER performance in alkaline media, achieving a small overpotential of 234 mV at 10 mA cm<sup>-2</sup> and satisfactory durability for over 70 hours.

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Publication Details

Journal
Chemical Communications
Published
2025-11-17
DOI
https://doi.org/10.1039/d5cc05689f
Primary Topic
Electrocatalysts for Energy Conversion
Type
article
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article

Engineering hierarchical porous carbon-supported Fe-doped cobalt phosphides from MOF templates for alkaline water oxidation

Jinjie Qian, Qipeng Li, Linchao Xu, Junliang Chen
Chemical Communications
Electrocatalysts for Energy Conversion
article

Engineering hierarchical porous carbon-supported Fe-doped cobalt phosphides from MOF templates for alkaline water oxidation

Jinjie Qian, Qipeng Li, Linchao Xu, Junliang Chen
article en

Abstract

A MOF-on-MOF strategy is utilized to synthesize Fe-doped cobalt phosphide nanoparticles within a porous N-doped carbon matrix (S-CoFeP). Detailed characterization confirms the successful formation of Co<sub>2</sub>P as the primary phase, with Fe incorporated as a beneficial dopant. S-CoFeP exhibits exceptional OER performance in alkaline media, achieving a small overpotential of 234 mV at 10 mA cm<sup>-2</sup> and satisfactory durability for over 70 hours.

Chemical CommunicationsVol. 62(1)
Wenzhou University (CN), Zhaotong University (CN), Wenzhou Vocational College of Science and Technology (CN)
Openalex Percentile: Top 76%
Electrocatalysts for Energy Conversion
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